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Abstract:
Sulfonimidoyl fluorides, the chiral aza-isosteres of sulfonyl fluorides, have gained increasing attention as a powerful linkage agent in the sulfur(VI)-fluoride exchange reaction (SuFEx). The hexavalent sulfonimidoyl fluorides are typically prepared from organosulfur in high oxidation states. We report herein an electrochemical approach using the readily available, bench-stable, yet underexplored tetravalent sulfinamidines without external chemical oxidants. The usefulness of the obtained sulfonimidoyl fluorides is demonstrated by their versatile SuFEx reactivity.
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ORGANIC LETTERS
ISSN: 1523-7060
Year: 2025
4 . 9 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 2
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