Copper-based homometallic and heterometallic binuclear complexes for electrocatalytic CO2 reduction - Details

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EI SCIE

Abstract：

A　series　of　copper-based　binuclear　complexes　were　synthesized　and　investigated　as　homogeneous　catalysts　for　the　electrochemical　reduction　of　carbon　dioxide.　Introduction　of　the　second　metal　site　systematically　tuned　the　electronic　structures　of　the　complexes　to　regulate　the　catalytic　performance,　giving　a　faradaic　efficiency　(FE)　of　71%　for　formic　acid　with　a　Cu-Cu　complex　and　an　FE　of　17%　for　hydrocarbons　with　a　Cu-Co　complex.

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[ 1 ] [Xie, Xin-Ling]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[ 2 ] [Chen, Feng]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[ 3 ] [Wang, Wen-Wen]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[ 4 ] [Lyu, Lei-Yan]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[ 5 ] [Sun, Meng-Jiao]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[ 6 ] [Zhang, Teng]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[ 7 ] [Cao, Rong]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[ 8 ] [Xie, Xin-Ling]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
[ 9 ] [Xie, Xin-Ling]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China
[ 10 ] [Wang, Wen-Wen]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China
[ 11 ] [Lyu, Lei-Yan]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China
[ 12 ] [Zhang, Teng]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China
[ 13 ] [Cao, Rong]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China
[ 14 ] [Chen, Feng]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[ 15 ] [Sun, Meng-Jiao]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[ 16 ] [Zhang, Teng]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[ 17 ] [Cao, Rong]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[ 18 ] [Wang, Wen-Wen]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China
[ 19 ] [Lyu, Lei-Yan]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China

Reprint 's Address：

[Zhang, Teng]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China;;[Cao, Rong]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China;;[Zhang, Teng]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China;;[Cao, Rong]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China;;[Zhang, Teng]Univ Chinese Acad Sci, Beijing 100049, Peoples R China;;[Cao, Rong]Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Email：

zhangteng@fjirsm.ac.cn |
rcao@fjirsm.ac.cn

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