Copper-based homometallic and heterometallic binuclear complexes for electrocatalytic CO2 reduction - Details

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A　series　of　copper-based　binuclear　complexes　were　synthesized　and　investigated　as　homogeneous　catalysts　for　the　electrochemical　reduction　of　carbon　dioxide.　Introduction　of　the　second　metal　site　systematically　tuned　the　electronic　structures　of　the　complexes　to　regulate　the　catalytic　performance,　giving　a　faradaic　efficiency　(FE)　of　71%　for　formic　acid　with　a　Cu-Cu　complex　and　an　FE　of　17%　for　hydrocarbons　with　a　Cu-Co　complex.　©　2025　The　Royal　Society　of　Chemistry.

Keyword：

Binary alloys Carbon dioxide Cobalt alloys Cobalt compounds Copper Copper alloys Copper compounds Electrolytic reduction Iron compounds Synthesis (chemical)

Community：

[ 1 ] [Xie, Xin-Ling]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 2 ] [Xie, Xin-Ling]College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 3 ] [Xie, Xin-Ling]Fujian College, University of the Chinese Academy of Sciences, Fuzhou; 350002, China
[ 4 ] [Chen, Feng]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 5 ] [Chen, Feng]University of the Chinese Academy of Sciences, Beijing; 100049, China
[ 6 ] [Wang, Wen-Wen]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 7 ] [Wang, Wen-Wen]Fujian College, University of the Chinese Academy of Sciences, Fuzhou; 350002, China
[ 8 ] [Wang, Wen-Wen]College of Chemistry and Materials Science, Fujian Normal University, Fuzhou; 350007, China
[ 9 ] [Lyu, Lei-Yan]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 10 ] [Lyu, Lei-Yan]Fujian College, University of the Chinese Academy of Sciences, Fuzhou; 350002, China
[ 11 ] [Lyu, Lei-Yan]College of Chemistry and Materials Science, Fujian Normal University, Fuzhou; 350007, China
[ 12 ] [Sun, Meng-Jiao]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 13 ] [Sun, Meng-Jiao]University of the Chinese Academy of Sciences, Beijing; 100049, China
[ 14 ] [Zhang, Teng]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 15 ] [Zhang, Teng]Fujian College, University of the Chinese Academy of Sciences, Fuzhou; 350002, China
[ 16 ] [Zhang, Teng]University of the Chinese Academy of Sciences, Beijing; 100049, China
[ 17 ] [Cao, Rong]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 18 ] [Cao, Rong]Fujian College, University of the Chinese Academy of Sciences, Fuzhou; 350002, China
[ 19 ] [Cao, Rong]University of the Chinese Academy of Sciences, Beijing; 100049, China

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Source ：

Chemical Communications

ISSN： 1359-7345

Year： 2025

Issue： 71

Volume： 61

Page： 13485-13488

4 . 3 0 0

JCR@2023

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ESI Highly Cited Papers on the List： 0 Unfold All

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