Photocatalytic　oxygen　reduction　to　industrially　valuable　hydrogen　peroxide　(H2O2)　in　the　presence　of　water　without　sacrificial　agents　is　highly　desirable　but　challenging　in　the　context　of　carbon　neutrality.　As　a　type　of　metal-free　photocatalysts,　covalent　triazine　polymers　(CTPs)　have　great　potential　in　photocatalytic　H2O2　evolution.　In　this　paper,　a　strategy　is　proposed　by　simultaneously　introducing　the　pyrene　(Py)　and　ether　(Et)　groups　into　covalent　triazine　polymers　to　fabricate　CTP-Py-Et.　The　introduction　of　pyrene　groups　increases　the　material＇s　overall　conjugation　degree,　thereby　enhancing　visible　light　absorption.　Meanwhile,　the　stronger　electronic　ability　of　the　pyrene　groups　establishes　more　charge　transfer　channels　through　the　electron　push-pull　effect,　and　more　free　charges　can　participate　in　the　photocatalytic　H2O2　evolution　from　water　and　oxygen.　The　incorporation　of　ether　groups　enhances　the　migration　efficiency　of　photogenerated　charges　and　effectively　boosts　the　selectivity　of　the　photocatalytic　one-step　two-electron　oxygen　reduction.　Compared　with　one-component　CTPs　(CTP-Py　and　CTP-Et),　CTP-Py-Et　possesses　an　outstanding　photocatalytic　H2O2　apparent　quantum　efficiency　of　13.2%　at　420　nm　and　an　objective　solar-to-chemical　conversion　(SCC)　efficiency　of　0.52%　at　298　K.　In　certain　instances,　a　high　H2O2　concentration　(3.22　mm,　1　h)　can　be　obtained　through　CTP-Py-Et,　prominently　surpassing　many　reported　polymer-based　photocatalysts.