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The tunnel structural titanates are absorbing as electrode materials for rechargeable batteries. However, the electronic conductivity and lithium-ion diffusion of these materials are seriously influenced by tunnel cations (Na+, K+), which are not acquainted imperfectly for their effect in lithium-ion batteries. In the present research, the layered structural K2Ti6O13(KTO) nanowires with a high aspect ratio and a large surface area have been synthesized through a general hydrothermal route. When applied as an anode material for lithium-ion intercalation, this material exhibited high and stable capacity, prominent cycling stability, and remarkable rate capabilities. Even at a high current density of 05 A g(-1), a large reversible capacity of 134.6 mA h g(-1) was acquired after 1000 cycles. These might be attributed to the fact that 1D nanostructural K2Ti6O13 with a high aspect ratio provides more surface reaction sites as well as increase the charge-transfer ability, and the presence of K+ in tunnels of K2Ti6O13 can efficiently improve the electronic conductivity and Li+ diffusivity. (C) 2020 Elsevier B.V. All rights reserved.
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JOURNAL OF ELECTROANALYTICAL CHEMISTRY
ISSN: 1572-6657
Year: 2020
Volume: 874
4 . 4 6 4
JCR@2020
4 . 1 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:160
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 6
SCOPUS Cited Count: 6
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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