Indexed by:
Abstract:
Electro-migration, diffusion-induced stress and their interaction have a significant impact on the electrode materials' performance and reliability. However, electro-migration is neglected in most existed models. In this work, a coupled electro-chemo-mechanical model with electro-migration is developed by using Gauss law, mass balance and equilibrium equation. The diffusion flux is separated into two parts: one is the gradient of concentration, and the other is the coupling terms including the concentration-hydrostatic pressure gradient term and the concentration-electric potential gradient term. Then some numerical simulations in a hollow spherical electrode of LiMn2O4 are carried out under potentiostatic and galvanostatic operations to capture how the electro-migration impacts on the lithium-ion concentration, radial stress and hoop stress. The numerical results reveal that the electro-migration plays a significant role in the diffusion (lithium-ion concentration) and mechanical deformation in the hollow spherical electrode for larger diffusion time; when the electrical potential at the inner surface is smaller than that at the outer surface, the charging efficiency will be improved and the stresses in the electrode will be descended.
Keyword:
Reprint 's Address:
Version:
Source :
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
ISSN: 1452-3981
Year: 2020
Issue: 7
Volume: 15
Page: 6012-6023
1 . 7 6 5
JCR@2020
1 . 3 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:160
JCR Journal Grade:4
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: