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author:

Liu, Xiaoming (Liu, Xiaoming.) [1] | Hu, Hai (Hu, Hai.) [2] | Suo, Yaohong (Suo, Yaohong.) [3] (Scholars:锁要红) | Yu, Pengfei (Yu, Pengfei.) [4] (Scholars:吁鹏飞)

Indexed by:

Scopus SCIE

Abstract:

Electro-migration, diffusion-induced stress and their interaction have a significant impact on the electrode materials' performance and reliability. However, electro-migration is neglected in most existed models. In this work, a coupled electro-chemo-mechanical model with electro-migration is developed by using Gauss law, mass balance and equilibrium equation. The diffusion flux is separated into two parts: one is the gradient of concentration, and the other is the coupling terms including the concentration-hydrostatic pressure gradient term and the concentration-electric potential gradient term. Then some numerical simulations in a hollow spherical electrode of LiMn2O4 are carried out under potentiostatic and galvanostatic operations to capture how the electro-migration impacts on the lithium-ion concentration, radial stress and hoop stress. The numerical results reveal that the electro-migration plays a significant role in the diffusion (lithium-ion concentration) and mechanical deformation in the hollow spherical electrode for larger diffusion time; when the electrical potential at the inner surface is smaller than that at the outer surface, the charging efficiency will be improved and the stresses in the electrode will be descended.

Keyword:

Diffusion induced stress Electro-chemo-mechanical coupling Electro-migration Lithium-ion battery

Community:

  • [ 1 ] [Liu, Xiaoming]Fuzhou Univ, Sch Mech Engn & Automat, Fuzhou 350108, Peoples R China
  • [ 2 ] [Hu, Hai]Fuzhou Univ, Sch Mech Engn & Automat, Fuzhou 350108, Peoples R China
  • [ 3 ] [Suo, Yaohong]Fuzhou Univ, Sch Mech Engn & Automat, Fuzhou 350108, Peoples R China
  • [ 4 ] [Yu, Pengfei]Fuzhou Univ, Sch Mech Engn & Automat, Fuzhou 350108, Peoples R China
  • [ 5 ] [Suo, Yaohong]Fujian Prov Univ, Fuzhou Univ, Key Lab Fluid Power & Intelligent Electrohydraul, Fuzhou 350116, Peoples R China
  • [ 6 ] [Yu, Pengfei]Xi An Jiao Tong Univ, Sch Aerosp, State Key Lab Strength & Vibrat Mech Struct, Xian 710049, Peoples R China

Reprint 's Address:

  • 锁要红 吁鹏飞

    [Suo, Yaohong]Fuzhou Univ, Sch Mech Engn & Automat, Fuzhou 350108, Peoples R China;;[Yu, Pengfei]Fuzhou Univ, Sch Mech Engn & Automat, Fuzhou 350108, Peoples R China;;[Suo, Yaohong]Fujian Prov Univ, Fuzhou Univ, Key Lab Fluid Power & Intelligent Electrohydraul, Fuzhou 350116, Peoples R China;;[Yu, Pengfei]Xi An Jiao Tong Univ, Sch Aerosp, State Key Lab Strength & Vibrat Mech Struct, Xian 710049, Peoples R China

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Source :

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE

ISSN: 1452-3981

Year: 2020

Issue: 7

Volume: 15

Page: 6012-6023

1 . 7 6 5

JCR@2020

1 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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