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author:

Wang, Junmei (Wang, Junmei.) [1] | Xu, Qinchao (Xu, Qinchao.) [2] | Liu, Manli (Liu, Manli.) [3] | Wang, Kefeng (Wang, Kefeng.) [4] | Wang, Zhijian (Wang, Zhijian.) [5] | Qu, Peng (Qu, Peng.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

Earth-abundant transition metal cocatalysts are promising rare and noble metal alternatives for efficient photocatalytic hydrogen evolution. Herein, a novel composite of ZIF-67 derived CoOx nanodots confined in a N, S co-doped graphitic nanosheet co-catalyst (CoOx@N, S-C) was successfully constructed via a one pot carbonization process. Through loading onto photosensitizer of CdS nanorods, the obtained CoOx@N, S-C/CdS composite exhibited an unprecedented H-2 production rate of 40.1 mmol g(-1) h(-1), which is 57, 20 and 1.7 times higher than that of CdS, N, S-C/CdS and CoOx/CdS, respectively. It was demonstrated that the excellent photocatalytic H-2 production performance arises from the synergetic effect between the confined ultrafine CoOx nanodots and N, S heteroatom co-doped graphitic carbon. This work shows considerable improvements over MOF derived materials as non-noble cocatalysts and provides significant motivation for new photocatalyst development for improving the conversion efficiency of solar energy to chemical fuels.

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Community:

  • [ 1 ] [Wang, Junmei]Shangqiu Normal Univ, Coll Chem & Chem Engn, Henan Engn Ctr New Energy Battery Mat, Shangqiu 476000, Peoples R China
  • [ 2 ] [Wang, Kefeng]Shangqiu Normal Univ, Coll Chem & Chem Engn, Henan Engn Ctr New Energy Battery Mat, Shangqiu 476000, Peoples R China
  • [ 3 ] [Qu, Peng]Shangqiu Normal Univ, Coll Chem & Chem Engn, Henan Engn Ctr New Energy Battery Mat, Shangqiu 476000, Peoples R China
  • [ 4 ] [Wang, Junmei]Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China
  • [ 5 ] [Liu, Manli]Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China
  • [ 6 ] [Xu, Qinchao]Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
  • [ 7 ] [Wang, Zhijian]Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
  • [ 8 ] [Wang, Zhijian]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • 蔡其洪

    [Qu, Peng]Shangqiu Normal Univ, Coll Chem & Chem Engn, Henan Engn Ctr New Energy Battery Mat, Shangqiu 476000, Peoples R China;;[Wang, Zhijian]Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China;;[Wang, Zhijian]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China

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Source :

SUSTAINABLE ENERGY & FUELS

ISSN: 2398-4902

Year: 2020

Issue: 4

Volume: 4

Page: 1954-1962

6 . 3 6 7

JCR@2020

5 . 0 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:196

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 12

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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