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author:

Qi, Ming-Yu (Qi, Ming-Yu.) [1] | Li, Yue-Hua (Li, Yue-Hua.) [2] | Zhang, Fan (Zhang, Fan.) [3] | Tang, Zi-Rong (Tang, Zi-Rong.) [4] (Scholars:唐紫蓉) | Xiong, Yujie (Xiong, Yujie.) [5] | Xu, Yi-Jun (Xu, Yi-Jun.) [6] (Scholars:徐艺军)

Indexed by:

EI Scopus SCIE

Abstract:

Cocatalyst loading is widely used as an approach in photocatalysis to expedite photoinduced charge separation and interfacial oxidation-reduction kinetics, which are crucial factors for affecting redox catalysis efficiency over semiconductor-based photocatalysts. However, tackling the key problem of cocatalyst loading position over heterojunction photocatalysts is still a great challenge. We herein report a facile and general light-tuning photodeposition strategy to realize site-directed spatial loading of diverse cocatalysts (MoS2, NixS, NixO, NixP, Pt) onto a CdS/TiO2 heterojunction photocatalyst, thereby abating surface charge recombination and markedly improving the photoredox-catalyzed activity of hydrogen evolution and selective oxidation of alcohol. This work highlights the wide scope of manipulating light to spatially regulate the cocatalyst loading position, thereby optimizing surface/interface charge recombination dynamics and ameliorating the net efficiency of charge separation and photoredox catalysis.

Keyword:

cocatalyst heterojunction photocatalyst photodeposition site-directed loading surface charge recombination

Community:

  • [ 1 ] [Qi, Ming-Yu]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
  • [ 2 ] [Li, Yue-Hua]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
  • [ 3 ] [Xu, Yi-Jun]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
  • [ 4 ] [Qi, Ming-Yu]Fuzhou Univ, Coll Chem, New Campus, Fuzhou 350116, Peoples R China
  • [ 5 ] [Li, Yue-Hua]Fuzhou Univ, Coll Chem, New Campus, Fuzhou 350116, Peoples R China
  • [ 6 ] [Zhang, Fan]Fuzhou Univ, Coll Chem, New Campus, Fuzhou 350116, Peoples R China
  • [ 7 ] [Tang, Zi-Rong]Fuzhou Univ, Coll Chem, New Campus, Fuzhou 350116, Peoples R China
  • [ 8 ] [Xu, Yi-Jun]Fuzhou Univ, Coll Chem, New Campus, Fuzhou 350116, Peoples R China
  • [ 9 ] [Xiong, Yujie]Univ Sci & Technol China, Sch Chem & Mat Sci, Collaborat Innovat Ctr Chem Energy Mat iChEM, Hefei 230026, Anhui, Peoples R China

Reprint 's Address:

  • 徐艺军

    [Xu, Yi-Jun]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China;;[Xu, Yi-Jun]Fuzhou Univ, Coll Chem, New Campus, Fuzhou 350116, Peoples R China

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Source :

ACS CATALYSIS

ISSN: 2155-5435

Year: 2020

Issue: 5

Volume: 10

Page: 3194-3202

1 3 . 0 8 4

JCR@2020

1 1 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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