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author:

Xu, Yihui (Xu, Yihui.) [1] | Chen, Qiaoling (Chen, Qiaoling.) [2] | Tian, Yishi (Tian, Yishi.) [3] | Wu, Wei (Wu, Wei.) [4] | You, Yi (You, Yi.) [5] (Scholars:游毅) | Weng, Zhiqiang (Weng, Zhiqiang.) [6]

Indexed by:

Scopus SCIE

Abstract:

A silver-catalyzed synthesis of 5-aryl-3-trifluoromethyl pyrazoles from reaction of various N'-benzylidene tolylsulfonohydrazides with ethyl 4,4,4-trifluoro-3-oxobutanoate is described. The reaction proceeds via sequential nucleophilic addition, intramolecular cyclization, elimination, and [1,5]-H shift steps to afford the trifluoromethylated pyrazole products in moderate to excellent yields. The reaction is compatible with a variety of functional groups. (C) 2019 Elsevier Ltd. All rights reserved.

Keyword:

Fluorine Pyrazole Silver Trifluoromethyl

Community:

  • [ 1 ] [Wu, Wei]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 2 ] [Wu, Wei]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Electrochem Energy Storage Ma, Fuzhou 350108, Peoples R China
  • [ 3 ] [Weng, Zhiqiang]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 4 ] [Weng, Zhiqiang]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Electrochem Energy Storage Ma, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 吴伟 翁志强

    [Wu, Wei]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China;;[Weng, Zhiqiang]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China

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Source :

TETRAHEDRON LETTERS

ISSN: 0040-4039

Year: 2020

Issue: 5

Volume: 61

2 . 4 1 5

JCR@2020

1 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 15

SCOPUS Cited Count: 17

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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