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author:

Wang, Ruo (Wang, Ruo.) [1] | Zhang, Tesen (Zhang, Tesen.) [2] | Zhang, Qianru (Zhang, Qianru.) [3] | Zheng, Mingwen (Zheng, Mingwen.) [4] | Xu, Kai (Xu, Kai.) [5] | Yan, Weitao (Yan, Weitao.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

With the development of the times, the energy density of cathodes can no longer meet the requirement of the society, which has greatly limited the commercialization process of Ni-rich cathodes. Doping combined with coating is a perfect approach to improve the performance of Ni-rich cathodes. In this paper, La was used as a modified element to realize doping in the layered host structure as well as La2O3 coating on the surface. To further enhance the interface stability of LiNi0.8Co0.1Mn0.1O2, F was also employed to modify the surface, so as to change the coating layer from oxide (La2O3) to fluoride (LaF3), which further improved the surface stability. Additionally, a series of testing instruments, including XRD, EDS mapping, and HRTEM, were employed, which suggested that a small amount of La was introduced into the host structure as a pillar to the stable layered structure, and there was an uniform LaF3 coating layer covered on the Ni-rich cathodes. As a result, the electrochemical performance of the cathodes was greatly improved, with the capacity retention of 86.63% and 80.79% after 200 cycles at 1 C rate and 300 cycles at 8 C rate, respectively; besides, the kinetics of lithium diffusion was also improved.

Keyword:

1Mn(0) 1O(2) 8Co(0) Cathode Coating Doping LiNi0 Ni-rich

Community:

  • [ 1 ] [Wang, Ruo]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Zhang, Tesen]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Zhang, Qianru]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
  • [ 4 ] [Zheng, Mingwen]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
  • [ 5 ] [Xu, Kai]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
  • [ 6 ] [Yan, Weitao]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China

Reprint 's Address:

  • 王若

    [Wang, Ruo]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China

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Source :

IONICS

ISSN: 0947-7047

Year: 2019

Issue: 3

Volume: 26

Page: 1165-1171

2 . 3 9 4

JCR@2019

2 . 4 0 0

JCR@2023

ESI Discipline: PHYSICS;

ESI HC Threshold:138

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 14

SCOPUS Cited Count: 13

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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