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Abstract:
Glass and glass-ceramic are one of the key sealing materials for solid oxide fuel cells (SOFCs) and they need to meet stringent requirements for long-term operation at high temperatures. Here, we report for the first time the incorporation of aluminum nitride (AlN) dopant into borosilicate glasses and glass-ceramics so as to tailor their basic properties and sealing performance. The results show the AlN-doped glass-ceramics exhibit remarkably enhanced thermal stability and chemical compatibility when adhering to Y2O3-ZrO2 electrolyte. The electrical conductivity is also significantly reduced by the AlN doping, and the conductivity of 15 wt.% AlN-doped glass-ceramic is nearly two orders of magnitude lower than that of the undoped glass-ceramic. This work indicates that AlN doping is an effective strategy to obtain a reliable borosilicate glass-ceramics for SOFCs.
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JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
ISSN: 0955-2219
Year: 2019
Issue: 14
Volume: 39
Page: 4194-4201
4 . 4 9 5
JCR@2019
5 . 8 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:236
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 7
SCOPUS Cited Count: 11
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
Affiliated Colleges: