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author:

Zhang, Xialan (Zhang, Xialan.) [1] | Wang, Weiqiang (Wang, Weiqiang.) [2] | Luo, Shiyuan (Luo, Shiyuan.) [3] | Lin, Qilang (Lin, Qilang.) [4] (Scholars:林起浪)

Indexed by:

EI Scopus SCIE

Abstract:

A novel oxidized hollow carbon sphere (OHCS) as absorbent for the removal of Pb2+ was fabricated from the mixture of coal-tar pitch and aluminum isopropoxide followed by nitric acid oxidation. The as prepared OHCSs were characterized by FESEM, TEM, BET, TG, FTIR and XPS, and meanwhile the effects of adsorption conditions on the Pb2+ removal were investigated by batch experiments. Results show that the OHCSs prepared possess discrete cage-like structures and well-defined inner/outer surface features, exhibiting vertically aligned graphene-like nanosheets on their surfaces with mesoporous nature and high hydrophobicity. The maximum absorption capacity for Pb2+ of the OHCSs can reach 280.79 mg g(-1) at the optimum condition. The adsorption kinetic of Pb2+ onto the OHCSs was found to be well modeled by pseudo-second-order kinetic model, and the experimental equilibrium data were represented well by Langmuir isotherm model. Moreover, the OHCSs still exhibit excellent adsorption ability and stability after recycling 5 times, indicating its excellent reusability performance. Overall, the OHCS is a promising adsorbent for Pb2+ removal. (C) 2019 Elsevier Inc. All rights reserved.

Keyword:

Acid treatment Adsorption Functionalization Lead Oxidized hollow carbon sphere

Community:

  • [ 1 ] [Zhang, Xialan]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Wang, Weiqiang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Luo, Shiyuan]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 4 ] [Lin, Qilang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China

Reprint 's Address:

  • 林起浪

    [Lin, Qilang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China

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Source :

JOURNAL OF COLLOID AND INTERFACE SCIENCE

ISSN: 0021-9797

Year: 2019

Volume: 553

Page: 484-493

7 . 4 8 9

JCR@2019

9 . 4 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 15

SCOPUS Cited Count: 16

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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