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author:

Ren, Shu (Ren, Shu.) [1] | Liu, Guojuan (Liu, Guojuan.) [2] | Wu, Xian (Wu, Xian.) [3] | Chen, Xinqing (Chen, Xinqing.) [4] | Wu, Minghong (Wu, Minghong.) [5] (Scholars:吴明红) | Zeng, Gaofeng (Zeng, Gaofeng.) [6] | Liu, Ziyu (Liu, Ziyu.) [7] | Sun, Yuhan (Sun, Yuhan.) [8]

Indexed by:

SCIE PKU CSCD

Abstract:

Hierarchical SAPO-34 crystals were synthesized by a facile acid etching post-treatment. Butterfly-shaped porous patterns on four side faces and hierarchical pores composed of micropores, mesopores and macropores were formed after a nitric acid or oxalic acid treatment. The catalytic performance of the hierarchical SAPO-34 for the methanol to olefins (MTO) process showed that the synergistic effect of the hierarchical pores and acid sites resulted in a longer catalyst lifetime (from 210 to 390 min for the acid treated SAPO-34) and higher selectivity to light olefins of 92%-94%. The ethylene selectivity can be adjusted between 37.4% and 51.5% by the pore size. No hierarchical SAPO-34 was obtained after a treatment with butanedioic acid, and with this sample, fast deactivation was detected after 100 min. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

Keyword:

Acid treatment Hierarchical pore Methanol to olefins SAPO-34 Single-run lifetime

Community:

  • [ 1 ] [Ren, Shu]Shanghai Univ, Coll Sci, Shanghai 201900, Peoples R China
  • [ 2 ] [Wu, Xian]Shanghai Univ, Coll Sci, Shanghai 201900, Peoples R China
  • [ 3 ] [Ren, Shu]Chinese Acad Sci, Shanghai Adv Res Inst, Key Lab Low Carbon Convers Sci & Engn, Shanghai 201210, Peoples R China
  • [ 4 ] [Liu, Guojuan]Chinese Acad Sci, Shanghai Adv Res Inst, Key Lab Low Carbon Convers Sci & Engn, Shanghai 201210, Peoples R China
  • [ 5 ] [Chen, Xinqing]Chinese Acad Sci, Shanghai Adv Res Inst, Key Lab Low Carbon Convers Sci & Engn, Shanghai 201210, Peoples R China
  • [ 6 ] [Zeng, Gaofeng]Chinese Acad Sci, Shanghai Adv Res Inst, Key Lab Low Carbon Convers Sci & Engn, Shanghai 201210, Peoples R China
  • [ 7 ] [Liu, Ziyu]Chinese Acad Sci, Shanghai Adv Res Inst, Key Lab Low Carbon Convers Sci & Engn, Shanghai 201210, Peoples R China
  • [ 8 ] [Sun, Yuhan]Chinese Acad Sci, Shanghai Adv Res Inst, Key Lab Low Carbon Convers Sci & Engn, Shanghai 201210, Peoples R China
  • [ 9 ] [Wu, Xian]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 201900, Peoples R China
  • [ 10 ] [Wu, Minghong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 201900, Peoples R China

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Source :

CHINESE JOURNAL OF CATALYSIS

ISSN: 0253-9837

CN: 21-1601/O6

Year: 2017

Issue: 1

Volume: 38

Page: 123-130

3 . 5 2 5

JCR@2017

1 5 . 7 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 78

SCOPUS Cited Count: 89

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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