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Abstract:
Hierarchical SAPO-34 crystals were synthesized by a facile acid etching post-treatment. Butterfly-shaped porous patterns on four side faces and hierarchical pores composed of micropores, mesopores and macropores were formed after a nitric acid or oxalic acid treatment. The catalytic performance of the hierarchical SAPO-34 for the methanol to olefins (MTO) process showed that the synergistic effect of the hierarchical pores and acid sites resulted in a longer catalyst lifetime (from 210 to 390 min for the acid treated SAPO-34) and higher selectivity to light olefins of 92%-94%. The ethylene selectivity can be adjusted between 37.4% and 51.5% by the pore size. No hierarchical SAPO-34 was obtained after a treatment with butanedioic acid, and with this sample, fast deactivation was detected after 100 min. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
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CHINESE JOURNAL OF CATALYSIS
ISSN: 0253-9837
CN: 21-1601/O6
Year: 2017
Issue: 1
Volume: 38
Page: 123-130
3 . 5 2 5
JCR@2017
1 5 . 7 0 0
JCR@2023
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 78
SCOPUS Cited Count: 89
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 5
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