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author:

Zhang, Jin (Zhang, Jin.) [1] | Wang, Xun (Wang, Xun.) [2] | Zhu, Yu (Zhu, Yu.) [3] | Huang, Zhenyu (Huang, Zhenyu.) [4] | Yu, Zhujing (Yu, Zhujing.) [5] | Bai, Yun (Bai, Yun.) [6] | Fan, Gongduan (Fan, Gongduan.) [7] (Scholars:范功端) | Wang, Peng (Wang, Peng.) [8] | Chen, Hao (Chen, Hao.) [9] | Su, Yiming (Su, Yiming.) [10] | Trujillo-Gonzalez, Juan Manuel (Trujillo-Gonzalez, Juan Manuel.) [11] | Hu, Bill X. (Hu, Bill X..) [12] | Krebs, Peter (Krebs, Peter.) [13] | Hua, Pei (Hua, Pei.) [14]

Indexed by:

Scopus SCIE

Abstract:

This study examines the adsorption and desorption characteristics of heavy metals in road dust (RD) for the aspect of integrated stormwater management. The chemical fractionations of Cu, Zn, Ni, and Cd were determined by a three-step sequential extraction protocol. Pseudo-first-order and Pseudo-second-order kinetic models, along with Langmuir, Freundlich, and Temkin isotherms were adopted to simulate the batch experimental data. The proportional shift of metals' chemical fractionations in original RD, adsorption equilibrium, and desorption equilibrium were determined. Results show that RD has a remarkable affinity to adsorb heavy metal within a short time. The adsorption processes were well described by the Pseudo-second-order kinetic model (R-2 = 0.98-0.99) and Freundlich isotherm (R-2 = 0.89-0.98) for most of the given metals indicating that the chemical adsorption was probably the rate-controlling step and the binding energy for each site was not identical. The maximum adsorption capacities for Cu, Cd, Zn, and Ni were 6300 mg kg(-1), 5800 mg kg(-1), 4000 mg kg(-1), and 3200 mg kg(-1), respectively. A linear fit to the equilibrium pH and the total amounts of the adsorbed metals indicates a strong pH-dependent adsorption. According to the proportional shift of metals' chemical fractionations during the adsorption and desorption processes, the exchangeable fractions of heavy metals in RD were irreversible. It suggests that a portion of the surface sites of RD would be not exchangeable once it was occupied.

Keyword:

Adsorption isotherm Adsorption kinetic Heavy metal Road dust Stormwater pollution

Community:

  • [ 1 ] [Zhang, Jin]Jinan Univ, Inst Groundwater & Earth Sci, Guangzhou 510632, Guangdong, Peoples R China
  • [ 2 ] [Wang, Xun]Jinan Univ, Inst Groundwater & Earth Sci, Guangzhou 510632, Guangdong, Peoples R China
  • [ 3 ] [Zhu, Yu]Jinan Univ, Inst Groundwater & Earth Sci, Guangzhou 510632, Guangdong, Peoples R China
  • [ 4 ] [Huang, Zhenyu]Jinan Univ, Inst Groundwater & Earth Sci, Guangzhou 510632, Guangdong, Peoples R China
  • [ 5 ] [Wang, Peng]Jinan Univ, Inst Groundwater & Earth Sci, Guangzhou 510632, Guangdong, Peoples R China
  • [ 6 ] [Hu, Bill X.]Jinan Univ, Inst Groundwater & Earth Sci, Guangzhou 510632, Guangdong, Peoples R China
  • [ 7 ] [Yu, Zhujing]Tech Univ Dresden, Inst Urban & Ind Water Management, D-01062 Dresden, Germany
  • [ 8 ] [Krebs, Peter]Tech Univ Dresden, Inst Urban & Ind Water Management, D-01062 Dresden, Germany
  • [ 9 ] [Bai, Yun]Chongqing Technol & Business Univ, Natl Res Base Intelligent Mfg Serv, Chongqing 400067, Peoples R China
  • [ 10 ] [Fan, Gongduan]Fuzhou Univ, Coll Civil Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 11 ] [Chen, Hao]Shanghai Acad Environm Sci, Dept Water Environm, Shanghai 200233, Peoples R China
  • [ 12 ] [Su, Yiming]UCLA, Dept Civil & Environm Engn, Los Angeles, CA 90095 USA
  • [ 13 ] [Trujillo-Gonzalez, Juan Manuel]Univ Llanos, Fac Ciencias Basicas & Ingn, ICAOC, Campus Barcelona, Villavicencio, Colombia
  • [ 14 ] [Hua, Pei]South China Normal Univ, SCNU Environm Res Inst, Guangdong Prov Key Lab Chem Pollut & Environm Saf, Guangzhou 510006, Guangdong, Peoples R China
  • [ 15 ] [Hua, Pei]South China Normal Univ, MOE, Key Lab Environm Theoret Chem, Guangzhou 510006, Guangdong, Peoples R China

Reprint 's Address:

  • [Zhang, Jin]Jinan Univ, Inst Groundwater & Earth Sci, Guangzhou 510632, Guangdong, Peoples R China;;[Hua, Pei]South China Normal Univ, MOE, Key Lab Environm Theoret Chem, Guangzhou 510006, Guangdong, Peoples R China

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Source :

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY

ISSN: 0147-6513

Year: 2019

Volume: 176

Page: 270-278

4 . 8 7 2

JCR@2019

6 . 2 0 0

JCR@2023

ESI Discipline: ENVIRONMENT/ECOLOGY;

ESI HC Threshold:188

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 36

SCOPUS Cited Count: 30

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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