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Carbon inlaid composites (C-Mn3O4/MnO) were prepared via igniting manganese acetate anhydrous ethanol solution in a beaker, and the resulting nanocomposites present homogeneous dispersion and stable property. The successful fabrication of the as-prepared samples was demonstrated by x-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM), and x-ray photoelectron spectroscopy (XPS). Various electrochemical measurements including cyclic voltammetry (CV), galvanostatic charge/discharge (GCD), and electrochemical impedance spectroscopy (EIS) were carried out. The maximum specific capacitance value of the C-Mn3O4/MnO composites can reach up to 204 F g(-1) at a current density of 1 A g(-1), which is much higher than that of Mn3O4/MnO composites (90 F g(-1)). The incorporated carbon improves the electrochemical performance and effectively decreases the charge transfer resistance of the composites (0.67 Omega) compared with pure Mn3O4/MnO composites (42.4 Omega). Surprisingly, as the number of cycles increase, the specific capacitance of C-Mn3O4/MnO composites become larger with a 188.3% of the initial specific capacitance value. This study develops a novel and facile method to fabricate composites of carbon and manganic oxide which have potential application in supercapacitor.
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MATERIALS RESEARCH EXPRESS
ISSN: 2053-1591
Year: 2019
Issue: 3
Volume: 6
1 . 9 2 9
JCR@2019
1 . 8 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:236
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 14
SCOPUS Cited Count: 15
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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