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author:

Lin, Li-Dan (Lin, Li-Dan.) [1] | Zhao, Dan (Zhao, Dan.) [2] | Li, Xin-Xiong (Li, Xin-Xiong.) [3] (Scholars:李新雄) | Zheng, Shou-Tian (Zheng, Shou-Tian.) [4] (Scholars:郑寿添)

Indexed by:

EI Scopus SCIE

Abstract:

During the past decade, research on the design and synthesis of zeolite-like metal-organic frameworks (ZMOFs) has developed greatly. As an important subclass of ZMOFs, zeolite-like cluster organic frameworks (ZCOFs) built from 4-connected metal-cluster secondary building units (SBUs) and appropriate linear organic ligand bridges have attracted sustained interest, because such materials not only integrate the merits of inorganic zeolites, ZMOFs, and metal clusters, including interesting topologies, high surface areas, extra-large cavities and channels, structural tunability, and unique physicochemical properties from various metal clusters, but also open up a new avenue to design and fabricate hybrid zeolite-like materials that have many potential applications in material sciences. In this review, recent developments in ZCOFs are summarized by classifying the ZCOFs into four categories according to the composition of the SBUs: 1) ZCOFs based on metal-halide cluster SBUs, 2) ZCOFs based on metal-oxygen cluster SBUs, 3) ZCOFs based on metal-chalcogen cluster SBUs, and 4) ZCOFs based on mixed types of metal-cluster SBUs. Besides, challenges associated with the design and synthesis of ZCOFs and the vast potential of this area are also discussed.

Keyword:

chalcogens cluster compounds cluster organic frameworks metal-halide clusters zeolite analogues

Community:

  • [ 1 ] [Lin, Li-Dan]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Li, Xin-Xiong]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Zheng, Shou-Tian]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Zhao, Dan]Fujian Normal Univ, Fuqing Branch, Fuqing 350300, Fujian, Peoples R China

Reprint 's Address:

  • 李新雄 郑寿添

    [Li, Xin-Xiong]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujian, Peoples R China;;[Zheng, Shou-Tian]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujian, Peoples R China

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Source :

CHEMISTRY-A EUROPEAN JOURNAL

ISSN: 0947-6539

Year: 2019

Issue: 2

Volume: 25

Page: 442-453

4 . 8 5 7

JCR@2019

3 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 35

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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