Two　zeolite-like　cluster　organic　frameworks　based　on　Cd-Cu/Mn-Cu　heterometallic　supertetrahedral　secondary　building　units　have　been　successfully　constructed　under　solvothermal　conditions,　namely,　Cu[Cd4Cu6(L)(4)(H2O)(18)](-)(Ac)(9)center　dot　DMA　center　dot　3H(2)O　(1),　and　Cu[Mn4Cu6(L)(4)(Ac)(3)(H2O)(12)](Ac)(6)center　dot　CH3CN　center　dot　13H(2)O　(2),　where　H3L=2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol,　Ac=CH3COO-,　DMA=N,N＇-dimethylacetamide.　Single-crystal　X-ray　structural　analysis　reveals　that　both　1　and　2　exhibit　3-dimensional　zeolite-like　architectures　with　similar　4-connected　components,　but　possess　definitely　different　topologies　of　diamondoid　(dia)　and　uncommon　lonsdaleite　(lon),　respectively.　1　and　2　represent　the　first　cases　of　zeolite-like　cluster　organic　frameworks　containing　Cd-Cu/Mn-Cu　heterometallic　supertetrahedral　secondary　building　units.　Furthermore,　the　magnetic　properties　and　porous　nature　of　1　and　2　were　also　studied.