Copper-mediated synthesis of alpha-trifluoromethylselenolated esters - Details

author：

Chen, Taotao (Chen, Taotao.) ^[1] | You, Yi (You, Yi.) ^[2] (Scholars：游毅) | Weng, Zhiqiang (Weng, Zhiqiang.) ^[3]

Indexed by：

Scopus SCIE

Abstract：

A　copper-mediated　synthesis　of　alpha-trifluoromethylselenolated　esters　was　developed.　Trifluoromethylselenolation　of　the　aromatic　and　aliphatic　alpha-diazo　esters　with　[(bpy)Cu(SeCF3)](2)　afforded　alpha-trifluoromethylselenolated　esters　in　good　to　excellent　yields.　Various　important　functional　groups　were　tolerated　in　the　ortho,　meta,　and　para　positions　of　the　phenyl　rings.

Keyword：

alpha-Diazo esters Copper Fluorine Trifluoromethylselenolation

Community：

[ 1 ] [Chen, Taotao]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environment, Fuzhou 350108, Fujian, Peoples R China
[ 2 ] [You, Yi]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environment, Fuzhou 350108, Fujian, Peoples R China
[ 3 ] [Weng, Zhiqiang]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environment, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address：

游毅翁志强
[You, Yi]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environment, Fuzhou 350108, Fujian, Peoples R China;;[Weng, Zhiqiang]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environment, Fuzhou 350108, Fujian, Peoples R China

Email：

youyi@fzu.edu.cn |
zweng@fzu.edu.cn

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