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author:

Wang, Zhihong (Wang, Zhihong.) [1] | Cao, Fenhui (Cao, Fenhui.) [2] | Chen, Kongfa (Chen, Kongfa.) [3] (Scholars:陈孔发) | Yan, Yingming (Yan, Yingming.) [4] | Chen, Yifu (Chen, Yifu.) [5] | Zhang, Yaohui (Zhang, Yaohui.) [6] | Zhu, Xingbao (Zhu, Xingbao.) [7] | Wei, Bo (Wei, Bo.) [8] | Xiong, Yueping (Xiong, Yueping.) [9] | Lv, Zhe (Lv, Zhe.) [10]

Indexed by:

EI Scopus SCIE

Abstract:

Cellular metals with the large surface/volume ratios and excellent electrical conductivity are widely applicable and have thus been studied extensively. It is highly desirable to develop a facile and cost-effective process for fabrication of porous metallic structures, and yet more so for micro/nanoporous structures. A direct-flame strategy is developed for in situ fabrication of micron-scale cellular architecture on a Ni metal precursor. The flame provides the required heat and also serves as a fuel reformer, which provides a gas mixture of H-2, CO, and O-2 for redox treatment of metallic Ni. The redox processes at elevated temperatures allow fast reconstruction of the metal, leading to a cellular structure on Ni wire. This process is simple and clean and avoids the use of sacrificial materials or templates. Furthermore, nanocrystalline MnO2 is coated on the microporous Ni wire (MPNW) to form a supercapacitor electrode. The MnO2/MPNW electrode and the corresponding fiber-shaped supercapacitor exhibit high specific capacitance and excellent cycling stability. Moreover, this work provides a novel strategy for the fabrication of cellular metals and alloys for a variety of applications, including catalysis, energy storage and conversion, and chemical sensing.

Keyword:

cellular architecture energy transfer flame redox process transition metal

Community:

  • [ 1 ] [Wang, Zhihong]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 2 ] [Yan, Yingming]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 3 ] [Chen, Yifu]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 4 ] [Zhang, Yaohui]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 5 ] [Zhu, Xingbao]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 6 ] [Wei, Bo]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 7 ] [Lv, Zhe]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 8 ] [Cao, Fenhui]Daqing Normal Univ, Sch Mechatron Engn, Daqing 163712, Heilongjiang, Peoples R China
  • [ 9 ] [Chen, Kongfa]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 10 ] [Xiong, Yueping]Harbin Inst Technol, MIIT Key Lab Crit Mat Technol New Energy Convers, Sch Chem & Chem Engn, 92 West Dazhi St, Harbin 150001, Heilongjiang, Peoples R China

Reprint 's Address:

  • [Wang, Zhihong]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China

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Related Keywords:

Source :

CHEMSUSCHEM

ISSN: 1864-5631

Year: 2018

Issue: 5

Volume: 11

Page: 985-993

7 . 8 0 4

JCR@2018

7 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 15

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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