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author:

Jiang, Xiancai (Jiang, Xiancai.) [1] (Scholars:江献财) | Sun, Yujun (Sun, Yujun.) [2] | Zhang, Hongxiang (Zhang, Hongxiang.) [3] | Hou, Linxi (Hou, Linxi.) [4] (Scholars:侯琳熙)

Indexed by:

EI Scopus SCIE

Abstract:

In this study, a series of novel quaternized poly(vinyl alcohol)/chitosan/molybdenum disulfide (QPVA/CS/ MoS2) anion exchange membranes (AEMs) were prepared for direct methanol alkaline fuel cell (DMAFC). The composite membrane was synthesized by adding different amounts of MoS2 nanosheets (0, 0.1, 0.2, 0.5 and 1 wt %) into QPVA/CS mixture solution and using the solution casting method. The crystallinity, thermal and mechanical properties, ion conductivity and resistance to methanol of the QPVA/CS/MoS2 membranes were characterized by X-ray diffraction, thermogravimetric analysis, tensile testing, ion exchange capacity, and methanol permeability measurements, respectively. The MoS2 was homogeneously dispersed in the membranes. The mechanical strength of the composite membranes was enhanced with the addition of MoS2. With the addition of 1.0 wt% MoS2, the QPVA/CS/MoS2 composite membrane has the lowest methanol permeability of 0.210 x10(-7) cm(2) . s(-1). This study confirmed that the novel QPVA/CS/MoS2 membrane would be a potential candidate for the application in DMAFCs.

Keyword:

Anion exchange membrane Chitosan Direct methanol alkaline fuel cells Molybdenum disulfide Quaternized poly(vinyl alcohol)

Community:

  • [ 1 ] [Jiang, Xiancai]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Sun, Yujun]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Zhang, Hongxiang]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Hou, Linxi]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 侯琳熙

    [Hou, Linxi]Fuzhou Univ, Sch Chem Engn, Fuzhou 350108, Fujian, Peoples R China

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Source :

CARBOHYDRATE POLYMERS

ISSN: 0144-8617

Year: 2018

Volume: 180

Page: 96-103

6 . 0 4 4

JCR@2018

1 0 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 55

SCOPUS Cited Count: 53

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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