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Abstract:
Three metal-free push pull type organic dyes QX19-21 based on indeno[1,2-b]indole donor have been synthesized for dye-sensitized solar cells (DSSCs). In order to obtain good cell performance, an ethynylene linker was inserted into the dye skeleton to extend pi-conjugated planar rigid structure and three hexyl groups were involved to prevent dye aggregation. The dyes QX19 and QX20 employing phenylene and thiophene as the pi-bridges were designed as a D-pi-A structure. As for the dye QX21, a benzothiadiazole was inserted as the secondary acceptor to construct as a D-A-pi-A structure. All three dyes based cells exhibited high photovoltages and good DSSC performances. A high PCE of 7.99% was obtained by the dye QX21 under AM 1.5G irradiation. Especially, the co-sensitization of QX21 with QX20 achieved the further improved PCE up to 8.37%. (C) 2017 Elsevier Ltd. All rights reserved.
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DYES AND PIGMENTS
ISSN: 0143-7208
Year: 2017
Volume: 141
Page: 93-102
3 . 7 6 7
JCR@2017
4 . 1 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:226
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 33
SCOPUS Cited Count: 36
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
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