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author:

Yan, Rucai (Yan, Rucai.) [1] | Qian, Xing (Qian, Xing.) [2] (Scholars:钱兴) | Jiang, Yiqing (Jiang, Yiqing.) [3] | He, Yiming (He, Yiming.) [4] | Hang, Yongjie (Hang, Yongjie.) [5] | Hou, Linxi (Hou, Linxi.) [6] (Scholars:侯琳熙)

Indexed by:

EI Scopus SCIE

Abstract:

Three metal-free push pull type organic dyes QX19-21 based on indeno[1,2-b]indole donor have been synthesized for dye-sensitized solar cells (DSSCs). In order to obtain good cell performance, an ethynylene linker was inserted into the dye skeleton to extend pi-conjugated planar rigid structure and three hexyl groups were involved to prevent dye aggregation. The dyes QX19 and QX20 employing phenylene and thiophene as the pi-bridges were designed as a D-pi-A structure. As for the dye QX21, a benzothiadiazole was inserted as the secondary acceptor to construct as a D-A-pi-A structure. All three dyes based cells exhibited high photovoltages and good DSSC performances. A high PCE of 7.99% was obtained by the dye QX21 under AM 1.5G irradiation. Especially, the co-sensitization of QX21 with QX20 achieved the further improved PCE up to 8.37%. (C) 2017 Elsevier Ltd. All rights reserved.

Keyword:

Charge transfer Dye-sensitized solar cells Ethynylene linker Indeno[1,2-b]indole Organic dyes Planar rigid structure

Community:

  • [ 1 ] [Yan, Rucai]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China
  • [ 2 ] [Qian, Xing]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China
  • [ 3 ] [Jiang, Yiqing]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China
  • [ 4 ] [He, Yiming]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China
  • [ 5 ] [Hang, Yongjie]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China
  • [ 6 ] [Hou, Linxi]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • 钱兴 侯琳熙

    [Qian, Xing]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China;;[Hou, Linxi]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China

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Source :

DYES AND PIGMENTS

ISSN: 0143-7208

Year: 2017

Volume: 141

Page: 93-102

3 . 7 6 7

JCR@2017

4 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:226

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 33

SCOPUS Cited Count: 36

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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