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Four metal-free organic dyes QX05-08 based on indoloquinoxaline and phenothiazine have been successfully designed and synthesized for dye-sensitized solar cells. The D-D-pi-A type dyes QX07 and QX08 consist of an indoloquinoxaline donor, a phenothiazine donor, a cyanoacrylic acid acceptor/anchoring group and a thiophene or furan pi-bridge. Other simple D-pi-A type dyes QX05 and QX06 based on indoloquinoxaline and phenothiazine respectively have also been synthesized for comparison. The D-D-pi-A type dyes QX07 and QX08 present good balanced structures and show excellent photoelectric properties. Especially, the dye QX07 with a thiophene unit as the pi-bridge exhibits the best photovoltaic performances in solar cells. A high power conversion efficiency up to 8.28% with a J(sc) of 15.3 mA cm(-2) and a V-oc of 757 mV have been achieved by the dye 0)107 using an iodine electrolyte under standard conditions. (C) 2016 Elsevier B.V. All rights reserved.
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JOURNAL OF POWER SOURCES
ISSN: 0378-7753
Year: 2016
Volume: 326
Page: 129-136
6 . 3 9 5
JCR@2016
8 . 1 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:324
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 70
SCOPUS Cited Count: 73
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3
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