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author:

Wu, Fangling (Wu, Fangling.) [1] | Wang, Jiabin (Wang, Jiabin.) [2] | Zhao, Qi (Zhao, Qi.) [3] | Jiang, Nan (Jiang, Nan.) [4] | Lin, Xucong (Lin, Xucong.) [5] (Scholars:林旭聪) | Xie, Zenghong (Xie, Zenghong.) [6] (Scholars:谢增鸿) | Li, Jianhua (Li, Jianhua.) [7] (Scholars:李建华) | Zhang, Qiqing (Zhang, Qiqing.) [8]

Indexed by:

EI Scopus SCIE

Abstract:

Based on in-tube solid-phase microextraction (in-tube SPME) using a hydrophobic poly (octadecyl methacrylate-co-ethylene dimethacrylate) [poly (OMA-co-EDMA)] monolith, a simple high performance liquid chromatography (HPLC) method has been developed for detection of trans-fatty acids (TFAs) as their fatty acid methyl esters (FAMEs). The poly (OMA-co-EDMA) monolithic column with high hydrophobicity was specially prepared for simultaneous microextraction, pre-separation and purification for the analytes. The pre-separation selectivity, the extraction efficiency, and the purification effect for FAMEs were investigated respectively. Furthermore, some operation parameters have been optimized in detail with respect to satisfactory extraction efficiency of the target compounds. Under the optimized conditions, the enrichment factors for model FAMEs were ranged from 58.3 to 70.9, wide linear range (0.01-1.00 mg/kg) and low detection limits (LODs) (3.0-7.1 mu g/kg) were achieved, respectively. In addition, recoveries of the method were in the range from 83.0 to 106.4% with low relative standard deviations (RSDs) of 3.2-4.7% (n =4) at spiking levels of 0.05, 0.25 and 0.5 mg/kg, respectively. Finally, the proposed method was successfully applied for detection of TFAs in practical samples, which possesses short time-consuming, low disturbance and high detection sensitivity. (C) 2016 Elsevier B.V. All rights reserved.

Keyword:

HPLC In-tube solid-phase microextraction Poly (OMA-co-EDMA) monolithic column Trans-fatty acids

Community:

  • [ 1 ] [Wu, Fangling]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350002, Peoples R China
  • [ 2 ] [Wang, Jiabin]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350002, Peoples R China
  • [ 3 ] [Zhao, Qi]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350002, Peoples R China
  • [ 4 ] [Jiang, Nan]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350002, Peoples R China
  • [ 5 ] [Li, Jianhua]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350002, Peoples R China
  • [ 6 ] [Zhang, Qiqing]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350002, Peoples R China
  • [ 7 ] [Wu, Fangling]Fudan Univ, Inst Laser Chem, Dept Chem, Shanghai 200433, Peoples R China
  • [ 8 ] [Lin, Xucong]Fuzhou Univ, Inst Food Safety & Environm Monitoring, Fuzhou 350108, Peoples R China
  • [ 9 ] [Xie, Zenghong]Fuzhou Univ, Inst Food Safety & Environm Monitoring, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 王家斌 张其清

    [Wang, Jiabin]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350002, Peoples R China;;[Zhang, Qiqing]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350002, Peoples R China

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Source :

JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES

ISSN: 1570-0232

Year: 2017

Volume: 1040

Page: 214-221

2 . 4 4 1

JCR@2017

2 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:226

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 24

SCOPUS Cited Count: 24

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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