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Abstract:
SmBaCo1.7Ni0.3O5+delta-xSm(0.2)Ce(0.8)O(1.9) (SBCN-xSDC, x = 0-50 wt.%) composite cathodes were prepared and characterized for potential use in intermediate-temperature solid oxide fuel cells (IT-SOFCs) based on an SDC electrolyte. The electrical conductivity and the thermal expansion coefficient (TEC) decreased with an increase in the SDC content of SBCN-xSDC composite cathodes. TEC values decreased from 15.59 x 10(-6) K-1 for SBCN to 13.17 x 10(-6) K-1 for SBCN-50SDC. Furthermore, the addition of SDC to the SBCN cathode improved its electrochemical performance. Among others, the SBCN-20SDC showed the lowest polarization resistance of 0.0272 Omega cm(2) at 800 degrees C; an anode-supported single-cell configuration of Ni-SDC/SDC/SBCN-20SDC obtained a maximum power density of 628 mW cm(-2) at 800 degrees C. Even when the content of SDC was raised up to 50 wt.%, the electrochemical performance of SBCN-SOSDC still exceeded that of pure SBCN. These results indicated that the SBCN-xSDC composite cathode is a promising material for ITSOFCs. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
ISSN: 0360-3199
Year: 2016
Issue: 2
Volume: 41
Page: 1176-1186
3 . 5 8 2
JCR@2016
8 . 1 0 0
JCR@2023
ESI Discipline: ENGINEERING;
ESI HC Threshold:177
JCR Journal Grade:1
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 15
SCOPUS Cited Count: 15
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
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