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author:

Ma Li-An (Ma Li-An.) [1] | Zheng Yong-An (Zheng Yong-An.) [2] | Wei Zhao-Hui (Wei Zhao-Hui.) [3] | Hu Li-Qin (Hu Li-Qin.) [4] | Guo Tai-Liang (Guo Tai-Liang.) [5] (Scholars:郭太良)

Indexed by:

EI Scopus SCIE PKU CSCD

Abstract:

A large amount of tin oxide (SnO2) nanowire arrays were synthesized on the flexible conductive carbon fiber substrate by thermal evaporation of tin powders in a tube furnace. The temperature, as well as the flow rate of the carrier N-2 gas and the reaction O-2 gas, plays an important role in defining the morphology of the SnO2 nanowires. Morphology and structure of the as-grown SnO2 samples are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). Results show that all the samples possess a typical rutile structure, and no other impurity phases are observed. The morphology changes from rod to wire with the increase of reaction temperature. Ratio of length to diameter of the nanowires increases first and then decreases with the flow ratio of N-2/O-2 gas. The optimum synthesis conditions of SnO2 nanowire are: reaction temperature 780 degrees C, N-2 and O-2 flow rates being 300 sccm and 3 sccm respectively. In our growth process, the nanowire grows mainly due to the vapor-liquid-solid (VLS) growth process, but both the VLS process and surface diffusion combined with a preferential growth mechanism play the important role in morphology evolution of the SnO2. Field emission measurements for Samples 1-6 are carried out in a vacuum chamber and a diode plate configuration is used. Relationship between the growth orientation, aspect ratio, density and uniformity of the arrays and field emission performances will be investigated first. Results reveal that the field emission performance of SnO2 nanostructures depends on their morphologies and array density. The turn-on electric field (at the current density of 10 mu A/cm(2)) decreases and the emission site density increases with tin oxide array density, and the turn-on electric field of Sample 5 (synthesized at 780 degrees C, nitrogen and oxygen flow rates being 300 sccm and 3 sccm respectively) is about 1.03 V/mu m at a working distance of 500 mu m. By comparison, for the turn-on electric fields of the not well-aligned SnO2 nanowire arrays we have 1.58, 2.13, 2.42, 1.82, and 1.97 V/mu m at 500 mu m. These behaviors indicate that such an ultralow turn-on field emission and marked enhancement in beta (similar to 4670) can be attributed to the better orientation, the good electric contact with the conducting fiber substrate where they grow, and the weaker field-screening effect. Our results demonstrate that well-aligned nanowire arrays, with excellent field-emission performance, grown on fiber substrate can provide the possibility of application in flexible vacuum electron sources.

Keyword:

chemical vapor deposition controllable morphology field emission nanostructures of tin oxide

Community:

  • [ 1 ] [Ma Li-An]Fujian Univ Technol, Sch Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Zheng Yong-An]Fujian Univ Technol, Sch Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Wei Zhao-Hui]Fujian Univ Technol, Sch Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Hu Li-Qin]Fuzhou Univ, Inst Optoelect & Displays Technol, Fuzhou 350108, Peoples R China
  • [ 5 ] [Guo Tai-Liang]Fuzhou Univ, Inst Optoelect & Displays Technol, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • [Ma Li-An]Fujian Univ Technol, Sch Mat Sci & Engn, Fuzhou 350108, Peoples R China

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Source :

ACTA PHYSICA SINICA

ISSN: 1000-3290

CN: 11-1958/O4

Year: 2015

Issue: 23

Volume: 64

0 . 6 7 7

JCR@2015

0 . 8 0 0

JCR@2023

ESI Discipline: PHYSICS;

ESI HC Threshold:200

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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