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author:

Zhong, Shui-ping (Zhong, Shui-ping.) [1] (Scholars:衷水平)

Indexed by:

EI Scopus SCIE CSCD

Abstract:

Gold bearing pyrite leaching was conducted in H2SO4-Fe2(SO4)3 system at different reaction temperatures, with different ferric ion concentrations, sulfuric acid concentrations and stirring speeds. The leaching kinetics and mechanism were studied. When the temperature ranged between 30-75 degrees C, the pyrite leaching was mainly controlled by chemical reaction with positive correlation to the ferric ion concentration. The activation energy obtained from Arrhenius empirical formula is 51.39 kJ/mol. The EDS and XPS analyses suggest that the oxidation of sulfur within pyrite is through a series of intermediate stages, and eventually is oxidized to sulphate accompanied with the formation of element sulfur. This indicates a thiosulfate oxidation pathway of the gold bearing pyrite oxidation in H2SO4-Fe-2(SO4)(3) system.

Keyword:

activation energy gold bearing pyrite H2SO4-Fe-2(SO4)(3) system leaching kinetics sulfur oxidation

Community:

  • [ 1 ] [Zhong, Shui-ping]Zijin Min Grp Co Ltd, Shanghang 364200, Peoples R China
  • [ 2 ] [Zhong, Shui-ping]Fuzhou Univ, Coll Zijin Min, Fuzhou 350108, Peoples R China
  • [ 3 ] [Zhong, Shui-ping]State Key Lab Comprehens Utilizat Low Grade Refra, Shanghang 364200, Peoples R China

Reprint 's Address:

  • 衷水平

    [Zhong, Shui-ping]Zijin Min Grp Co Ltd, Shanghang 364200, Peoples R China

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Source :

TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA

ISSN: 1003-6326

CN: 43-1239/TG

Year: 2015

Issue: 10

Volume: 25

Page: 3461-3466

1 . 3 4

JCR@2015

4 . 7 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:335

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 21

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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