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Abstract:
Gold bearing pyrite leaching was conducted in H2SO4-Fe2(SO4)3 system at different reaction temperatures, with different ferric ion concentrations, sulfuric acid concentrations and stirring speeds. The leaching kinetics and mechanism were studied. When the temperature ranged between 30-75 degrees C, the pyrite leaching was mainly controlled by chemical reaction with positive correlation to the ferric ion concentration. The activation energy obtained from Arrhenius empirical formula is 51.39 kJ/mol. The EDS and XPS analyses suggest that the oxidation of sulfur within pyrite is through a series of intermediate stages, and eventually is oxidized to sulphate accompanied with the formation of element sulfur. This indicates a thiosulfate oxidation pathway of the gold bearing pyrite oxidation in H2SO4-Fe-2(SO4)(3) system.
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TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
ISSN: 1003-6326
CN: 43-1239/TG
Year: 2015
Issue: 10
Volume: 25
Page: 3461-3466
1 . 3 4
JCR@2015
4 . 7 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:335
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 21
SCOPUS Cited Count: 21
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: