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author:

Hua Nengbin (Hua Nengbin.) [1] | Chen Wenzhe (Chen Wenzhe.) [2] | Liu Xiaoli (Liu Xiaoli.) [3] | Zhang Tao (Zhang Tao.) [4]

Indexed by:

EI Scopus SCIE

Abstract:

The non-isothermal and isothermal crystallization kinetics of Zr72.5Al10Fe17.5 glassy alloy was investigated using differential scanning calorimeter (DSC). Under non-isothermal heating condition, the primary phase in the initial crystallization is Zr6Al2 Fe phase and the final crystallized products consist of Zr6Al2Fe, Zr2Fe and alpha-Zr phases. The apparent activation energy for crystallization estimated using the Kissinger method is 342.1 +/- 8.1 kJ/mol. The local activation energy decreased with the increase in the crystallization volume fraction during nonisothermal crystallization. Under isothermal heating condition, the average Avrami exponent of about 2.76 implies a mainly diffusion-controlled three-dimensional growth with an increasing nucleation rate. The local activation energy for isothermal crystallization shows a different variation trend from that for non-isothermal crystallization, indicating different nucleation-and-growth mechanisms for the two crystallizaiton conditions.

Keyword:

activation energy avrami exponent crystallization glassy alloys

Community:

  • [ 1 ] [Hua Nengbin]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou 350116, Peoples R China
  • [ 2 ] [Chen Wenzhe]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou 350116, Peoples R China
  • [ 3 ] [Hua Nengbin]Fujian Univ Technol, Dept Mat Sci & Engn, Fuzhou 350118, Peoples R China
  • [ 4 ] [Chen Wenzhe]Fujian Univ Technol, Dept Mat Sci & Engn, Fuzhou 350118, Peoples R China
  • [ 5 ] [Liu Xiaoli]Fujian Univ Technol, Dept Mat Sci & Engn, Fuzhou 350118, Peoples R China
  • [ 6 ] [Zhang Tao]Beihang Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Aerosp Mat & Performance, Beijing 100191, Peoples R China

Reprint 's Address:

  • 花能斌

    [Hua Nengbin]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou 350116, Peoples R China;;[Hua Nengbin]Fujian Univ Technol, Dept Mat Sci & Engn, Fuzhou 350118, Peoples R China

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Source :

JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION

ISSN: 1000-2413

CN: 42-1680/TB

Year: 2016

Issue: 1

Volume: 31

Page: 191-196

0 . 4 4 7

JCR@2016

1 . 3 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:324

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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