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Photocatalytic active material ZnS was grown on the surfaces of magnetic cores, Fe3O4 and NiCO2O4, by the solvothermal method to produce magnetically separable Fe3O4@ZnS and NiCo2O4@ZnS core-shell photocatalysts. These hydrogen production photocatalysts can be recycled by magnetic force for repeated hydrogen generation. The morphology, crystalline property, magnetic property, photocatalytic activity, and magnetic separation capability of the core-shell photocatalysts were studied. Fe3O4@ZnS based core-shell photocatalysts had better magnetic separation capability than the NiCo2O4@ZnS analog. The optimized photocatalytic hydrogen production rates of NiCo2O4@ZnS and Fe3O4 ZnS core shell nanoparticles reached 880 mu mol h(-1) g(-1) and 3900 mu mol h(-1) g(-1), respectively. Both photocatalysts can be recycled by magnetic force. Recycled photocatalysts exhibited good hydrogen generation performance after being recycled for three times. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
ISSN: 0360-3199
Year: 2015
Issue: 35
Volume: 40
Page: 11436-11443
3 . 2 0 5
JCR@2015
8 . 1 0 0
JCR@2023
ESI Discipline: ENGINEERING;
ESI HC Threshold:183
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 48
SCOPUS Cited Count: 51
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: