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author:

Hong Lihua (Hong Lihua.) [1] | Zhang Hua (Zhang Hua.) [2] | Tang Qunhua (Tang Qunhua.) [3] | Wen Jiancheng (Wen Jiancheng.) [4] | Dai Pinqiang (Dai Pinqiang.) [5]

Indexed by:

EI Scopus SCIE PKU CSCD

Abstract:

Al0.5CrCoFeNi high entropy alloy was prepared by vacuum arc melting in a high-purity argon atmosphere. The oxidation experiments were performed at the temperatures of 800, 900, 1000 and 1100 degrees C for 100 h, and the corresponding oxidation kinetics curves have been tested. The structure and morphology of oxide layer have been studied by adopting the analytical methods, such as XRD and SEM. The results show that oxide films forming at 800 degrees C and 900 degrees C were complete and compact, and have excellent oxidation resistance. However, the oxide films forming at 1000 degrees C and 1100 degrees C become much thicker and have a large number of cracks and holes, which result into poor oxidation resistance. Interface reactions played a mast role at the early stage of oxidation, but with the growing of oxide films, diffusion process played an important role increasingly, and became the control factor for continue oxidizing. Then, one or multiple kinds of alloy elements oxide precipitated on the surface, and formed inner spinel oxide of NiCr2O4, CoCr2O4 and Fe(Cr,Al)(2)O-4. During the high temperature oxidation process, N-2 will react with Al to generate AIN particles. The further oxidizing has made AIN particles oxidized again and N-2 escaped. Finally, the holes with the AIN particles shape have appeared.

Keyword:

high entropy alloy high temperature oxidation oxide film

Community:

  • [ 1 ] [Hong Lihua]Fuzhou Univ, Fuzhou 350108, Peoples R China
  • [ 2 ] [Zhang Hua]Fuzhou Univ, Fuzhou 350108, Peoples R China
  • [ 3 ] [Tang Qunhua]Fuzhou Univ, Fuzhou 350108, Peoples R China
  • [ 4 ] [Wen Jiancheng]Fuzhou Univ, Fuzhou 350108, Peoples R China
  • [ 5 ] [Dai Pinqiang]Fuzhou Univ, Fuzhou 350108, Peoples R China
  • [ 6 ] [Hong Lihua]Fujian Univ Technol, Fuzhou 350108, Peoples R China
  • [ 7 ] [Dai Pinqiang]Fujian Univ Technol, Fuzhou 350108, Peoples R China
  • [ 8 ] [Zhang Hua]Fuzhou Ustron Optoelect Mat Co Ltd, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 戴品强

    [Dai Pinqiang]Fuzhou Univ, Sch Mat Sci & Engn, Fuzhou 350108, Peoples R China

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Source :

RARE METAL MATERIALS AND ENGINEERING

ISSN: 1002-185X

CN: 61-1154/TG

Year: 2015

Issue: 2

Volume: 44

Page: 424-428

0 . 2 3 6

JCR@2015

0 . 6 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:335

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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