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author:

Lu, Haixia (Lu, Haixia.) [1] (Scholars:吕海霞) | An, Hongtao (An, Hongtao.) [2] | Xie, Zenghong (Xie, Zenghong.) [3] (Scholars:谢增鸿)

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Scopus SCIE

Abstract:

A new ion-imprinted carboxymethyl chitosan-functionalized silica gel sorbent was synthesized by surface imprinting technique using Cd(II) as the template, carboxymethyl chitosan (CMCS) as the functional monomer and glutaraldehyde as the cross-linking agent for the selective adsorption of Cd(II) from aqueous solution. The optimum batch experimental conditions (pH, amount of adsorbent, contact time) and column experimental conditions (concentration and volume of elution solution) were evaluated. The maximum static adsorption capacity of the ion-imprinted sorbent for Cd(II) was 20.7 mg/g. The enrichment factor of Cd(II)-imprinted polymer for Cd(II) was 257. The relative selectivity factor values of Cd(II)/Pb(II), Cd(II)/Co(II) were 5.3 and 1.5, respectively. The recoveries of water samples were about 98.0-104.0% (R.S.D. <= 0.8). The proposed method was successfully applied to determination of Cd(II) in water samples with satisfactory. (c) 2013 Elsevier B.V. All rights reserved.

Keyword:

Cadmium(II) Carboxymethyl chitosan Flame atomic absorption spectrometry Ion-imprinted polymers

Community:

  • [ 1 ] [Lu, Haixia]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [An, Hongtao]Fuzhou Univ, Inst Food Safety & Environm Monitoring, Fuzhou 350108, Peoples R China
  • [ 3 ] [Xie, Zenghong]Fuzhou Univ, Inst Food Safety & Environm Monitoring, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 吕海霞

    [Lu, Haixia]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China

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Source :

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES

ISSN: 0141-8130

Year: 2013

Volume: 56

Page: 89-93

3 . 0 9 6

JCR@2013

7 . 7 0 0

JCR@2023

ESI Discipline: BIOLOGY & BIOCHEMISTRY;

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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