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author:

Zhang, Teng (Zhang, Teng.) [1] | Zou, Qi (Zou, Qi.) [2] | Zhang, Jing (Zhang, Jing.) [3] | Tang, Dian (Tang, Dian.) [4] (Scholars:唐电) | Yang, Hiswen (Yang, Hiswen.) [5]

Indexed by:

EI Scopus SCIE

Abstract:

In this paper, a ceramic sealant (CaB2O4) is developed for the self-healing design of solid oxide fuel cells (SOFCs). The interface between this ceramic sealant and the anode-supported electrolyte, e.g., 8 mole% yttria-stabilized zirconia (8YSZ), remains intact after sixty thermal cycles from 800 degrees C to room temperature. An in situ observation verifies that the micro-indentation on the surface of this material can be healed when heating from room temperature to 920 degrees C at a heating rate of 40 degrees C min(-1). In addition, the weight loss of CaB2O4, held at 850 degrees C in air for 28 days, decreases from 3.26 +/- 0.73 for sealed species to 0.81 +/- 0.04 mg cm(-2) for fully crystallized species; meanwhile, the weight loss of CaB2O4, held at 850 degrees C in wet forming gas (30 vol% water vapor) for 28 days, decreases from 14.80 +/- 1.83 for sealed species to 6.36 +/- 0.64 mg cm(-2) for fully crystallized species. Combining with the good mechanical stability and thermal-stability, this self-healing ceramic sealant provides promising solution for the sealing challenge of planar SOFCs. (C) 2012 Elsevier B.V. All rights reserved.

Keyword:

Ceramic sealant Mechanical stability Planar solid oxide fuel cells Self-healing Thermal stability

Community:

  • [ 1 ] [Zhang, Teng]Fuzhou Univ, Inst Mat Res, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Zou, Qi]Fuzhou Univ, Inst Mat Res, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Zhang, Jing]Fuzhou Univ, Inst Mat Res, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Tang, Dian]Fuzhou Univ, Inst Mat Res, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Yang, Hiswen]Natl United Univ, Dept Mat Sci & Engn, Miaoli 36003, Taiwan

Reprint 's Address:

  • 张腾

    [Zhang, Teng]Fuzhou Univ, Inst Mat Res, Fuzhou 350108, Fujian, Peoples R China

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Source :

JOURNAL OF POWER SOURCES

ISSN: 0378-7753

Year: 2012

Volume: 204

Page: 122-126

4 . 6 7 5

JCR@2012

8 . 1 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 13

SCOPUS Cited Count: 14

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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