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author:

Zhang, Teng (Zhang, Teng.) [1] | Zou, Qi (Zou, Qi.) [2] | Zhang, Jing (Zhang, Jing.) [3] | Tang, Dian (Tang, Dian.) [4] | Yang, Hiswen (Yang, Hiswen.) [5]

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EI

Abstract:

In this paper, a ceramic sealant (CaB2O4) is developed for the self-healing design of solid oxide fuel cells (SOFCs). The interface between this ceramic sealant and the anode-supported electrolyte, e.g., 8 mole% yttria-stabilized zirconia (8YSZ), remains intact after sixty thermal cycles from 800 °C to room temperature. An in situ observation verifies that the micro-indentation on the surface of this material can be healed when heating from room temperature to 920 °C at a heating rate of 40 °C min-1. In addition, the weight loss of CaB2O 4, held at 850 °C in air for 28 days, decreases from 3.26 ± 0.73 for sealed species to 0.81 ± 0.04 mg cm-2 for fully crystallized species; meanwhile, the weight loss of CaB2O 4, held at 850 °C in wet forming gas (30 vol% water vapor) for 28 days, decreases from 14.80 ± 1.83 for sealed species to 6.36 ± 0.64 mg cm-2 for fully crystallized species. Combining with the good mechanical stability and thermal-stability, this self-healing ceramic sealant provides promising solution for the sealing challenge of planar SOFCs. © 2012 Elsevier B.V. All rights reserved.

Keyword:

Boron compounds Calcium compounds Ceramic materials Electrolytes Mechanical stability Sealants Self-healing materials Solid oxide fuel cells (SOFC) Thermodynamic stability Yttria stabilized zirconia Yttrium oxide Zirconia

Community:

  • [ 1 ] [Zhang, Teng]Institute for Materials Research, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 2 ] [Zou, Qi]Institute for Materials Research, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 3 ] [Zhang, Jing]Institute for Materials Research, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 4 ] [Tang, Dian]Institute for Materials Research, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 5 ] [Yang, Hiswen]Department of Materials Science and Engineering, National United University, Miao-Li 36003, Taiwan

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Source :

Journal of Power Sources

ISSN: 0378-7753

Year: 2012

Volume: 204

Page: 122-126

4 . 6 7 5

JCR@2012

8 . 1 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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