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author:

Yu Chang-Lin (Yu Chang-Lin.) [1] | Cao Fang-Fang (Cao Fang-Fang.) [2] | Shu Qing (Shu Qing.) [3] | Bao Yu-Long (Bao Yu-Long.) [4] | Xie Zhi-Peng (Xie Zhi-Peng.) [5] | Yu Jimmy C (Yu Jimmy C.) [6] | Yang Kai (Yang Kai.) [7]

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

A series of novel bismuth oxyhalide Ag/BiOX (X=Cl, Br, I) composite photocatalysts were synthesized by a solution-based photodeposited method at room temperature. The resulting products were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), photoluminescence (PL) emission spectroscopy, UV-Vis diffuse reflectance spectroscopy (DRS), and N-2 physical adsorption. The photocatalytic activity of the samples was evaluated by photocatalytic degradation of acid orange II under visible light (420 nm<lambda<660 nm) irradiation. Analysis by N-2 physical adsorption showed that deposition of Ag decreased the specific surface area of the catalyst. UV-Vis DRS analysis indicated that the presence of Ag could result in surface plasmon absorption, effectively increasing the visible light absorption ability of BiOCl and BiOBr. Furthermore, PL analysis indicated that Ag could effectively suppress the recombination of photogenerated electron (e(-))-hole (h(+)) pairs of Ag/BiOX. Activity testing indicated that the deposition of an optimal amount of 1%-2% (w, mass fraction) Ag brought about 10, 13, and 2 fold increases in the photocatalytic activity of BiOCl, BiOBr, and BiOI, respectively. The high photocatalytic performance of the composite photocatalysts could be attributed to the strong visible light absorption, silver plasmon photocatalysis role and the recombination restraint of the e(-)/h(+) pairs resulting from the presence of metal silver particles.

Keyword:

Acid orange II Bismuth oxyhalide Photocatalysis Promotion Silver deposition Visible light

Community:

  • [ 1 ] [Yu Chang-Lin]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
  • [ 2 ] [Cao Fang-Fang]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
  • [ 3 ] [Shu Qing]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
  • [ 4 ] [Bao Yu-Long]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
  • [ 5 ] [Xie Zhi-Peng]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
  • [ 6 ] [Yang Kai]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
  • [ 7 ] [Cao Fang-Fang]Fuzhou Univ, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base, Fuzhou 350002, Peoples R China
  • [ 8 ] [Yu Jimmy C]Chinese Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

Reprint 's Address:

  • [Yu Chang-Lin]Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China

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Source :

ACTA PHYSICO-CHIMICA SINICA

ISSN: 1000-6818

CN: 11-1892/O6

Year: 2012

Issue: 3

Volume: 28

Page: 647-653

0 . 8 6 9

JCR@2012

1 0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 26

SCOPUS Cited Count: 33

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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