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author:

Ni Jun (Ni Jun.) [1] (Scholars:倪军) | Wang Rong (Wang Rong.) [2] (Scholars:王榕) | Kong Fanhua (Kong Fanhua.) [3] | Zhang Tianfu (Zhang Tianfu.) [4] | Lin Jianxin (Lin Jianxin.) [5] (Scholars:林建新) | Lin Bingyu (Lin Bingyu.) [6] (Scholars:林炳裕) | Wei Kemei (Wei Kemei.) [7]

Indexed by:

EI Scopus SCIE PKU CSCD

Abstract:

The effect of alkaline-earth oxides as promoters on Ru/AC (AC = activated carbon) catalysts was explored. Alkaline-earth metal oxides can reduce the agglomeration of ruthenium particles at high temperatures, which increases the amount of available ruthenium. The influence of the Mg promoter on the distribution and activity of the Ru/AC catalyst were investigated by CO chemisorption, X-ray diffraction, and energy dispersive spectrometry and by an activity test for ammonia synthesis. The results show that a specific quantity of magnesium significantly promotes the uniform distribution of Ba and Ru on the surface of AC, which enhances catalytic activity. The introduction of Mg significantly improved the size of the Ru particles and increased the Ru surface area. The distribution and interaction were improved greatly for the Ba promoter and the Ru precursor on the surface of the AC because of the addition of the Mg promoter. The introduction of magnesium to Ru-Ba-K/AC significantly improved the utilization ratio of the noble metals and the performance-price ratio.

Keyword:

activated carbon ammonia synthesis barium magnesium ruthenium

Community:

  • [ 1 ] [Ni Jun]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Wang Rong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Lin Jianxin]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Lin Bingyu]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Wei Kemei]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Kong Fanhua]Petrochina Co Ltd, Petrochem Res Inst, Beijing 100029, Peoples R China
  • [ 7 ] [Zhang Tianfu]Petrochina Co Ltd, Petrochem Res Inst, Beijing 100029, Peoples R China

Reprint 's Address:

  • 王榕

    [Wang Rong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalysts, Fuzhou 350002, Fujian, Peoples R China

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Source :

CHINESE JOURNAL OF CATALYSIS

ISSN: 0253-9837

CN: 21-1601/O6

Year: 2011

Issue: 3

Volume: 32

Page: 436-439

1 . 1 7 1

JCR@2011

1 5 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 8

SCOPUS Cited Count: 10

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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