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author:

Liu Zhong-Qian (Liu Zhong-Qian.) [1] | Zhao Ya-Feng (Zhao Ya-Feng.) [2] | Huang Xi-He (Huang Xi-He.) [3] (Scholars:黄细河) | Li Hao-Hong (Li Hao-Hong.) [4] (Scholars:李浩宏) | Huang Chang-Cang (Huang Chang-Cang.) [5] (Scholars:黄长沧)

Indexed by:

SCIE CSCD

Abstract:

Two cadmium arsonate coordination polymers, Cd(HL1)(2) (1, H2L1 = 4-aminophenylarsonatic acid) and Cd(H2L2)(2)center dot 2H(2)O (2, H3L2 = 2-(4-arsonphenylamino)acetic acid), have been synthesized and characterized by IR and single-crystal X-ray diffraction. Crystal data for 1: triclinic, space group P (1) over bar with a = 5.7559(12), b = 7.0903(14), c = 8.9925(18) angstrom, alpha = 89.04(3), beta = 80.79(3), gamma = 85.09(3)degrees, D-c = 2.496 g.cm(-3), mu = 6.095 mm(-1), F(000) = 260, Z = 1, the final R = 0.0574 and wR = 0.1376 for 1489 observed reflections with I > 2 sigma(I). And those for 2: monoclinic, space group P2(1)/c with a = 4.7595(10), b = 9.925(2), c = 22.609(5) angstrom, beta = 91.81(3)degrees, D-c = 2.167 g.cm(-3), mu = 4.168 mm(-1), F(000) = 684, Z = 2, the final R = 0.0335 and wR = 0.0815 for 2340 observed reflections with I > 2 sigma(I). The structure of 1 shows a two-dimensional layer consisting of inorganic chains of {CdN2(AsO3)(2)} along the a axis linking with the phenyl groups. These layers are further linked through strong interlayer hydrogen bonding interaction to form a three-dimensional hydrogen bond supramolecular architecture. Compound 2 has inorganic chains of {CdO2(AsO3)(2)} similar to 1, which connect with four adjacent inorganic chains forming a three-dimensional framework.

Keyword:

arsonates cadmium(II) crystal structure syntheses

Community:

  • [ 1 ] [Liu Zhong-Qian]Fuzhou Univ, Dept Chem, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 2 ] [Zhao Ya-Feng]Fuzhou Univ, Dept Chem, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 3 ] [Huang Xi-He]Fuzhou Univ, Dept Chem, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 4 ] [Li Hao-Hong]Fuzhou Univ, Dept Chem, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 5 ] [Huang Chang-Cang]Fuzhou Univ, Dept Chem, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 黄长沧

    [Huang Chang-Cang]Fuzhou Univ, Dept Chem, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Peoples R China

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Source :

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2010

Issue: 11

Volume: 29

Page: 1724-1730

0 . 6 2 4

JCR@2010

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

Online/Total:325/10051306
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