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Abstract:
The title compound 1 has been synthesized by the reaction of H2MoO4, CdC12, H3PO4, KF, piperazine hexahydrate and water in aqueous solution under mild hydrothermal conditions. Single-crystal X-ray analysis reveals that the title compound crystallizes in the triclinic system, space group P (1) over bar with a = 14.049(3), b = 15.972(3), c = 20.043(4) angstrom, alpha = 85.82(3), beta = 81.28(3), gamma = 67.15(3)degrees, V = 4095.9(14) angstrom(3), M-r = 3204.62, Z = 2, D-c = 2.598 g/cm(3), mu = 2.360 mm(-1), F(000) = 3124, the final R = 0.0314, wR = 0.0826 and S = 0.989 for 18592 observed reflections with I > 2 sigma(I). The crystal packing is stabilized by N-H center dot center dot center dot O and O-H center dot center dot center dot O intra- and intermolecular hydrogen bonds to form an infinite 3D network.
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CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN: 0254-5861
CN: 35-1112/TQ
Year: 2009
Issue: 12
Volume: 28
Page: 1677-1680
0 . 5 4 4
JCR@2009
5 . 9 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:4
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 1
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
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