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author:

Chen Wu-Hua (Chen Wu-Hua.) [1] | Zhou Yun-Long (Zhou Yun-Long.) [2] | Ta Hong-Gui (Ta Hong-Gui.) [3] | Hu Zhi-Biao (Hu Zhi-Biao.) [4] | Qiu Ze-Hai (Qiu Ze-Hai.) [5] | Zhang Li (Zhang Li.) [6] | Zeng Qing-Xin (Zeng Qing-Xin.) [7] (Scholars:曾庆新)

Indexed by:

SCIE CSCD

Abstract:

The title compound 1 has been synthesized by the reaction of H2MoO4, CdC12, H3PO4, KF, piperazine hexahydrate and water in aqueous solution under mild hydrothermal conditions. Single-crystal X-ray analysis reveals that the title compound crystallizes in the triclinic system, space group P (1) over bar with a = 14.049(3), b = 15.972(3), c = 20.043(4) angstrom, alpha = 85.82(3), beta = 81.28(3), gamma = 67.15(3)degrees, V = 4095.9(14) angstrom(3), M-r = 3204.62, Z = 2, D-c = 2.598 g/cm(3), mu = 2.360 mm(-1), F(000) = 3124, the final R = 0.0314, wR = 0.0826 and S = 0.989 for 18592 observed reflections with I > 2 sigma(I). The crystal packing is stabilized by N-H center dot center dot center dot O and O-H center dot center dot center dot O intra- and intermolecular hydrogen bonds to form an infinite 3D network.

Keyword:

crystal structure hydrothermal synthesis polyoxometalate

Community:

  • [ 1 ] [Zhou Yun-Long]Fuzhou Univ, Dept Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Zhang Li]Fuzhou Univ, Dept Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Zeng Qing-Xin]Fuzhou Univ, Dept Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Chen Wu-Hua]Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China
  • [ 5 ] [Zhou Yun-Long]Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China
  • [ 6 ] [Ta Hong-Gui]Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China
  • [ 7 ] [Hu Zhi-Biao]Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China
  • [ 8 ] [Qiu Ze-Hai]Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China

Reprint 's Address:

  • 曾庆新

    [Zeng Qing-Xin]Fuzhou Univ, Dept Chem, Fuzhou 350002, Fujian, Peoples R China

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Source :

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2009

Issue: 12

Volume: 28

Page: 1677-1680

0 . 5 4 4

JCR@2009

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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