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Abstract：
A new metal-oxo cluster supported transition metal complex, [Cu(en)(2)(H2O)](2)[Cu(en)(2)](0.5)((Mo8V6VO42)-V-VI-V-IV-O-V{Cu(en)(2)}] has been synthesized under hydrothermal conditions. Its structure was determined by single-crystal X-ray diffraction. The compound crystallizes in the triclinic system, space group P (1) over bar (No. 2). a = 12.245(5), b = 12.669(5), c = 20.949(8) angstrom, alpha = 77.120(13), beta = 78.107(17), gamma = 65.560(14)degrees, V = 2860(2) angstrom Z = 2. The metal-oxo cluster contains it novel bicapped a-Keggin structure unit and a [Cu(en)(2)](2+) unit covalently bonded to the [Mo8V7,O-42](7-) cluster.
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ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN： 0044-2313
Year： 2005
Issue： 8
Volume： 631
Page： 1528-1531
1 . 2 0 2
JCR@2005
1 . 1 0 0
JCR@2023
ESI Discipline： CHEMISTRY;
JCR Journal Grade：3
Cited Count：
WoS CC Cited Count： 7
SCOPUS Cited Count：
ESI Highly Cited Papers on the List： 0 Unfold All
WanFang Cited Count：
Chinese Cited Count：
30 Days PV： 1
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