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author:

Xu, XP (Xu, XP.) [1] (Scholars:许小平) | Li, ZQ (Li, ZQ.) [2] | Huang, XH (Huang, XH.) [3] (Scholars:黄细河) | Wang, XX (Wang, XX.) [4] (Scholars:王绪绪) | Fu, XZ (Fu, XZ.) [5] (Scholars:付贤智) | Andreas, H (Andreas, H.) [6] | Gerd, M (Gerd, M.) [7]

Indexed by:

EI Scopus SCIE CSCD

Abstract:

In this paper, a model is presented to correlate and predict the swelling behavior of hydrogels in aqueous solutions of electrolytes. The model is a combination of VERS-model, "phantom network" theory and "free-volume" contribution. The VERS-model is used to calculate Gibbs excess energy; "phantom network" theory to describe the elastic properties of polymer network, and "free-volume" contribution to account for additional difference in the size of the species. To test the model, a series of N-isopropylacrylamide based hydrogels are synthesized by free radical polymerization in oxygen-free, deionized water at 25degreesC under nitrogen atmosphere. Then, the degree of swelling of all investigated gels as well as the partition of the solute between the gel phase and the surrounding coexisting liquid phase are measured in aqueous solution of sodium chloride. The model test demonstrates that the swelling behavior correlated and predicted by the model agrees with the experimental data within the experimental uncertainty. The phase transition appeared in the experiment, and the influences of the total mass fraction of polymerizable materials xi(gel) as well as the mole fraction of the crosslinking agent y(CR) on the swelling behavior of IPAAm-gels can also be predicted correctly. All these show the potential of such model for correlation and prediction of the swelling behavior of hydrogels in aqueous solutions of electrolytes.

Keyword:

aqueous solution of NaCl N-isopropylacrylamide swelling of hydrogel VERS-model

Community:

  • [ 1 ] Fuzhou Univ, Dept Chem Engn, Fuzhou 350002, Peoples R China
  • [ 2 ] Univ Kaiserslautern, Lehrstuhl Tech Thermodynam, D-67663 Kaiserslautern, Germany

Reprint 's Address:

  • 许小平

    [Xu, XP]Fuzhou Univ, Dept Chem Engn, Fuzhou 350002, Peoples R China

Email:

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Source :

CHINESE JOURNAL OF CHEMICAL ENGINEERING

ISSN: 1004-9541

CN: 11-3270/TQ

Year: 2004

Issue: 3

Volume: 12

Page: 425-432

0 . 3 3 7

JCR@2004

3 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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