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author:

Zhu, YP (Zhu, YP.) [1] | Zhao, JX (Zhao, JX.) [2] (Scholars:赵剑曦) | You, Y (You, Y.) [3] (Scholars:游毅)

Indexed by:

SCIE CSCD

Abstract:

The effects of n-propanol, n-butanol, n-pentanol and n-hexanol on the micellization of quaternary-ammonium dimeric surfactant C-12-2-C-12 . 2Br have been investigated using conductivity and steady fluorescence measurements. The results show that the surfactant and the alcohols form mixed micelles with addition of alcohols. In the mixed micelles, the alkyl chains of the alcohol molecules penetrate into the micelle interior and the hydroxyl groups lie in the palisade layer of the micelles, which weaken the electrostatic repulsion between the ionic head groups of the surfactants and result in a decrease of cme and an increase of the ionization degree of the micelle. The effects become more striking with increasing the alkyl chain length of the alcohol molecules.

Keyword:

alcohol effects dimeric surfactant micellization quaternary-ammonium

Community:

  • [ 1 ] Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 朱永平

    [Zhu, YP]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

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Source :

ACTA CHIMICA SINICA

ISSN: 0567-7351

CN: 31-1320/O6

Year: 2002

Issue: 6

Volume: 60

Page: 1001-1005

0 . 5 3 6

JCR@2002

1 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

Online/Total:217/10051819
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