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author:

Cheng, SY (Cheng, SY.) [1] (Scholars:程树英) | Chen, YQ (Chen, YQ.) [2] | Huang, CH (Huang, CH.) [3] | Chen, GN (Chen, GN.) [4] (Scholars:陈国南)

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CPCI-S EI Scopus

Abstract:

In this paper, SnS films were cathodically electrodeposited on ITO glass substrates from aqueous solution containing 5mM SnSO4 and 25mM Na2S2O3 with pH of 2-3. When the deposition potential (E) was varied from -0.60 to -1.1V vs SCE, the corresponding SnS films were characterized with X-ray diffractograms, microstructure and composition analysis. It was found that, the composition ratio Sn/S of the film varied with E, the ratio Sn/S significantly increased and exceeded 1 at E more cathodic than -0.75V vs SCE, and the ratio Sn/S significantly decreased and was less than 1 at E larger than -0.7V vs SCE. The stoichiometric SnS film was synthesized at -0.72-0.75V vs SCE. The structural and optical properties of the film have been studied. The X-ray diffraction pattern of the film showed that it was polycrystalline and of orthorhombic structure. The estimated optical bandgap energy was 1.31eV.

Keyword:

deposition voltage electrodeposition tin sulfide(SnS)

Community:

  • [ 1 ] Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 程树英

    [Cheng, SY]Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

Email:

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Source :

Advanced Materials and Devices for Sensing and Imaging II

ISSN: 0277-786X

Year: 2005

Volume: 5633

Page: 308-314

Language: English

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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