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author:

Pang, Aiying (Pang, Aiying.) [1] | Li, Jinlong (Li, Jinlong.) [2] | Wei, Xiao-Feng (Wei, Xiao-Feng.) [3] | Ruan, Zhi-Wu (Ruan, Zhi-Wu.) [4] | Yang, Ming (Yang, Ming.) [5] | Chen, Zhong-Ning (Chen, Zhong-Ning.) [6]

Indexed by:

EI

Abstract:

Fabricating electron transport layers at low temperatures is challenging but highly desired in the field of flexible perovskite solar cells (f-PSCs). In this study, highly uniform cerium oxide (CeOx) films prepared by the UV-O3 treatment have been successfully applied as the electron transport layer (ETL) in methylammonium lead halide (CH3NH3PbI3) perovskite-based f-PSCs. Under AM 1.5 G sunlight with 100 mW cm-2, these cells exhibited an open-circuit voltage (Voc) of 0.98 V, a short-circuit current density (Jsc) of 19.42 mA cm-2, a fill factor (FF) of 0.72 and power conversion efficiency (PCE) of 14.63%. The PCE was much higher than that of the control planar CeOx ETL (PCE ∼ 9.08%) prepared at a low temperature (80 °C) without the UV-O3 treatment, and this was ascribed to the improved CeOx film, enhanced light absorption and suppressed charge recombination. The cells that bend at 15 mm of radius showed excellent stability with less than 10% reduction in PCE after 500 cycles of repeated bending at ambient temperature. The charge-transmission kinetic parameters and long-term stability of the CeOx-based f-PSCs were analyzed as well. This journal is © The Royal Society of Chemistry.

Keyword:

Cerium oxide Conversion efficiency Electron transport properties Film preparation Lead compounds Light absorption Open circuit voltage Oxide films Oxides Perovskite Perovskite solar cells Temperature

Community:

  • [ 1 ] [Pang, Aiying]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou Fujian; 350002, China
  • [ 2 ] [Pang, Aiying]College of Chemistry and Materials, Fujian Normal University, Fuzhou Fujian; 350007, China
  • [ 3 ] [Li, Jinlong]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou Fujian; 350002, China
  • [ 4 ] [Li, Jinlong]College of Chemistry, Fuzhou University, Fuzhou Fujian; 350002, China
  • [ 5 ] [Wei, Xiao-Feng]National Engineering Research Center of Chemical Fertilizer Catalyst, School of Chemical Engineering, Fuzhou University, Fujian; 350002, China
  • [ 6 ] [Ruan, Zhi-Wu]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou Fujian; 350002, China
  • [ 7 ] [Ruan, Zhi-Wu]College of Chemistry and Materials, Fujian Normal University, Fuzhou Fujian; 350007, China
  • [ 8 ] [Yang, Ming]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou Fujian; 350002, China
  • [ 9 ] [Yang, Ming]College of Chemistry and Materials, Fujian Normal University, Fuzhou Fujian; 350007, China
  • [ 10 ] [Chen, Zhong-Ning]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou Fujian; 350002, China
  • [ 11 ] [Chen, Zhong-Ning]College of Chemistry and Materials, Fujian Normal University, Fuzhou Fujian; 350007, China

Reprint 's Address:

  • [chen, zhong-ning]state key laboratory of structural chemistry, fujian institute of research on the structure of matter, chinese academy of sciences, fuzhou fujian; 350002, china;;[chen, zhong-ning]college of chemistry and materials, fujian normal university, fuzhou fujian; 350007, china

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Source :

Nanoscale Advances

Year: 2020

Issue: 9

Volume: 2

Page: 4062-4069

4 . 5 5 3

JCR@2020

4 . 6 0 0

JCR@2023

ESI HC Threshold:196

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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