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In order to uncover the fractal characteristics of adsorption-pores of sulfide ores, representative samples were collected from Dongguashan Copper Mine to carry out the low temperature nitrogen adsorption experiment. The QuadraSorb Si specific surface area and pore size distribution analyzer were used to analyze the characteristics of different pore sizes (0.250, 0.125 and 0.088 mm in diameter, respectively). FHH (Frenkel-Halsey-Hill) model was performed to calculate their fractal dimensions; the relationship between gas adsorptive capacity of sulfide ores and its pore structure parameter & its fractal dimension and further was analyzed. The results show that the smaller particle size of sulfide ores is associated with the larger microporous specific surface area and pore volume; gas adsorption on sulfide ores generally occurs in the micropores varying from 3 nm to 4 nm and the higher the fractal dimension, the more the micropore. The specific surface area becomes larger accordingly, and the pore surface is rougher and tends to three-dimensional space. The value of fractal dimension indicates the adsorptive capacity of samples, and the fractal dimension is positively correlated with the adsorptive capacity. Therefore, the high fractal dimension and the complex pore structures caused by the decrease of smaller particle size of sulfide ores can lead to the great possibility of oxidation and spontaneous combustion. © 2017, Central South University Press. All right reserved.
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Journal of Central South University (Science and Technology)
ISSN: 1672-7207
CN: 43-1426/N
Year: 2017
Issue: 8
Volume: 48
Page: 2180-2186
Cited Count:
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3
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