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author:

Zeng, Cheng (Zeng, Cheng.) [1] | Lin, Qilang (Lin, Qilang.) [2] | Fang, Changqing (Fang, Changqing.) [3] | Xu, Dongwei (Xu, Dongwei.) [4] | Ma, Zhichao (Ma, Zhichao.) [5]

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EI

Abstract:

Co-pyrolysis product of coal-tar pitch and rosin was used as a precursor to prepare high surface area activated carbons (ACs) by KOH activation. The influences of AC precursor origin, KOH/AC precursor weight ratio and activation time on the pore characteristics of the ACs were investigated, and meanwhile their electrochemical performance was studied. The results show that adding rosin results in a decrease in the C/H atomic ratio of AC precursor as well as a significant increase in its mesophase content, which favors the porosity development in ACs during KOH activation. The effect of adding rosin on the porosity characteristics of the ACs can be illustrated by increases in the BET surface area from 1846 to 2847 m2/g and the total pore volume from 1.09 to 1.57 cm3/g. In addition, the ACs possess good electrochemical performance, as indicated by that they have a maximum specific capacitance of 203 F/g and exhibit good rectangular-shaped I-V curves in cyclic voltammetry. © 2013 Elsevier B.V. All rights reserved.

Keyword:

Activated carbon Chemical activation Coal Coal tar Cyclic voltammetry Molecular weight Porosity Potassium hydroxide Pyrolysis

Community:

  • [ 1 ] [Zeng, Cheng]College of Materials Science and Engineering, Fuzhou University, Fuzhou 350116, China
  • [ 2 ] [Lin, Qilang]College of Materials Science and Engineering, Fuzhou University, Fuzhou 350116, China
  • [ 3 ] [Fang, Changqing]College of Printing and Packing Engineering, Xi'An University of Technology, Xi'an 710048, China
  • [ 4 ] [Xu, Dongwei]College of Materials Science and Engineering, Fuzhou University, Fuzhou 350116, China
  • [ 5 ] [Ma, Zhichao]College of Materials Science and Engineering, Fuzhou University, Fuzhou 350116, China

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Source :

Journal of Analytical and Applied Pyrolysis

ISSN: 0165-2370

Year: 2013

Volume: 104

Page: 372-377

3 . 0 7

JCR@2013

5 . 8 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 37

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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