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author:

Chen, Xiaomei (Chen, Xiaomei.) [1] | Cai, Zhixiong (Cai, Zhixiong.) [2] | Huang, Zhiyong (Huang, Zhiyong.) [3] | Oyama, Munetaka (Oyama, Munetaka.) [4] | Jiang, Yaqi (Jiang, Yaqi.) [5] | Chan, Xi (Chan, Xi.) [6]

Indexed by:

EI

Abstract:

An enzyme-free oxalic acid (OA) electrochemical sensor was assembled using a platinum nanoparticle-loaded graphene nanosheets (PtNPGNs)-modified electrode. The PtNPGNs, with a high yield of PtNPs dispersed on the graphene nanosheets, were successfully achieved by a green, rapid, one-step and template-free method. The resulting PtNPGNs were characterized by transmission electron microscopy (TEM), high-resolution TEM, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and an X-ray diffraction technique. Electrochemical oxidation of OA on the PtNPGNs-modified electrode was investigated by cyclic voltammetry and differential pulse voltammetry methods. Based on the results, the modified electrode exhibited high electrochemical activity with well-defined peaks of OA oxidation and a notably decreased overpotential compared to the bare or even the GNs-modified electrode. Under optimized conditions, a good linear response was observed for the concentration of OA and its current response was in the range of 0.1-15 mM and 15-50 mM with a detection limit (S/N = 3) of 10 μM. Furthermore, the electrochemical sensor presented good characteristics in terms of stability and reproducibility, promising the applicability of the sensor in practical analysis. © 2013 The Royal Society of Chemistry.

Keyword:

Cyclic voltammetry Electrochemical electrodes Electrochemical oxidation Electrochemical sensors Energy dispersive spectroscopy Enzyme electrodes Graphene High resolution transmission electron microscopy Nanoparticles Nanosheets Oxalic acid Platinum X ray photoelectron spectroscopy

Community:

  • [ 1 ] [Chen, Xiaomei]College of Biological Engineering, Jimei University, Xiamen 361021, China
  • [ 2 ] [Chen, Xiaomei]Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8520, Japan
  • [ 3 ] [Cai, Zhixiong]Ministry of Education, Key Laboratory of Analysis and Detection Technology for Food Safety, Fuzhou University, Fuzhou 350002, China
  • [ 4 ] [Huang, Zhiyong]College of Biological Engineering, Jimei University, Xiamen 361021, China
  • [ 5 ] [Oyama, Munetaka]Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8520, Japan
  • [ 6 ] [Jiang, Yaqi]State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen 361005, China
  • [ 7 ] [Chan, Xi]State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen 361005, China

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Source :

Nanoscale

ISSN: 2040-3364

Year: 2013

Issue: 13

Volume: 5

Page: 5779-5783

6 . 7 3 9

JCR@2013

5 . 8 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 37

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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