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The effect on field emission properties of carbon nanotube (CNT) oxidized by HNO3 and HNO3-H2SO4 were investigated by TEM, Raman and XPS. The results showed that the impurity of catalyzer and amorphous carbon had been eliminated by the oxidation of HNO3 or HNO3-H2SO4. For the effect of oxidization and dehydration of H2SO4, the higher disorder degree and more disfigurement density were obtained of carbon nanotubes treated by HNO3-H2SO4 than that of those treated by HNO3, with the oxidized groups such as C-OH, CO and COOH in existence of surface. The turn-on field of carbon nanotubes treated by HNO3-H2SO4 is 1.1V/μm, which is lower than that of those treated by HNO3 as 1.7V/μm. The corresponding emission current density is 1.8 and 4.2mA/cm2 for carbon nanotubes treated by HNO3 and HNO3-H2SO4, respectively, while the applied field increased to 3.0V/μm.
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Journal of Functional Materials
ISSN: 1001-9731
CN: 50-1099/TH
Year: 2010
Issue: 9
Volume: 41
Page: 1529-1531,1535
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 2
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