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author:

Ye, Yun (Ye, Yun.) [1] (Scholars:叶芸) | You, Yu-Xiang (You, Yu-Xiang.) [2] | Tang, Qiao-Zhi (Tang, Qiao-Zhi.) [3] | Guo, Tai-Liang (Guo, Tai-Liang.) [4] (Scholars:郭太良)

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Abstract:

The effect on field emission properties of carbon nanotube (CNT) oxidized by HNO3 and HNO3-H2SO4 were investigated by TEM, Raman and XPS. The results showed that the impurity of catalyzer and amorphous carbon had been eliminated by the oxidation of HNO3 or HNO3-H2SO4. For the effect of oxidization and dehydration of H2SO4, the higher disorder degree and more disfigurement density were obtained of carbon nanotubes treated by HNO3-H2SO4 than that of those treated by HNO3, with the oxidized groups such as C-OH, CO and COOH in existence of surface. The turn-on field of carbon nanotubes treated by HNO3-H2SO4 is 1.1V/μm, which is lower than that of those treated by HNO3 as 1.7V/μm. The corresponding emission current density is 1.8 and 4.2mA/cm2 for carbon nanotubes treated by HNO3 and HNO3-H2SO4, respectively, while the applied field increased to 3.0V/μm.

Keyword:

Acids Amorphous carbon Carbon nanotubes Field emission Oxidation X ray photoelectron spectroscopy

Community:

  • [ 1 ] [Ye, Yun]College of Physics and Telecommunication Engineering, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [You, Yu-Xiang]College of Physics and Telecommunication Engineering, Fuzhou University, Fuzhou 350002, China
  • [ 3 ] [Tang, Qiao-Zhi]College of Physics and Telecommunication Engineering, Fuzhou University, Fuzhou 350002, China
  • [ 4 ] [Guo, Tai-Liang]College of Physics and Telecommunication Engineering, Fuzhou University, Fuzhou 350002, China

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Source :

Journal of Functional Materials

ISSN: 1001-9731

CN: 50-1099/TH

Year: 2010

Issue: 9

Volume: 41

Page: 1529-1531,1535

Cited Count:

WoS CC Cited Count:

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ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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