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author:

Cao, Chunyan (Cao, Chunyan.) [1] | Dong, Huilong (Dong, Huilong.) [2] | Liang, Fanghua (Liang, Fanghua.) [3] | Zhang, Yu (Zhang, Yu.) [4] | Zhang, Wei (Zhang, Wei.) [5] | Wang, Hailou (Wang, Hailou.) [6] | Shao, Huaiyu (Shao, Huaiyu.) [7] | Liu, Hongchao (Liu, Hongchao.) [8] | Dong, Kai (Dong, Kai.) [9] | Tang, Yuxin (Tang, Yuxin.) [10] (Scholars:汤育欣) | Lai, Yuekun (Lai, Yuekun.) [11] (Scholars:赖跃坤) | Ge, Mingzheng (Ge, Mingzheng.) [12]

Indexed by:

EI SCIE

Abstract:

Huge volume expansion and inferior electrical conductivity are the two main obstacles to limit the practical applications of high-capacity molybdenum disulfide (MoS2) materials, which has been recognized as ideal anode materials for rechargeable lithium-ion batteries. Herein, an interfacial reinforcement structure design is proposed by conformally growing few-layered MoS2 nanosheets on carbon coated ultralong TiO2 nanotubes (TiO2@C@MoS2) to stabilize the solid electrolyte interface (SEI) of MoS2-based electrode. The interlayer carbon coating on TiO2 nanotubes effectively improves the interfacial contact between MoS2 nanosheets and TiO2 nanotubes by forming Ti-O-C and C-S chemical bonds between TiO2/carbon coating and MoS2/carbon coating, respectively, avoiding MoS2 nanosheets detaching from TiO2 nanotubes. Meanwhile, the carbon coating serves as a buffering cushion to alleviate mechanical strain at the interface of MoS2 nanosheets and TiO2 nanotubes. Besides, it enhances the adsorption performance of Li ions on the surface of MoS2 and at the interface sites between MoS2 and TiO2. While three-dimensional rigid TiO2 nanotubes networks work as mechanical support to suppress reaggregating and restacking of MoS2 nanosheets, and provide fast transportation expressways for electrons/ions. Thus, the TiO2@C@MoS2 electrode exhibits ultrafast charge/discharge capability, a high reversible capacity of 1150 mAh g(-1) at 0.1 A g(-1), and superior cycling performance with 90% capacity retention after 1500 cycles at 1.0 A g(-1). This interfacial reinforcement structure design provides valuable experience to benefit rational design of alloy/conversion-typed materials electrode with high-performance.

Keyword:

Interfacial reinforcement Lithium-ion battery MoS2 nanosheets Solid-electrolyte interfaces TiO2 nanotubes

Community:

  • [ 1 ] [Cao, Chunyan]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China
  • [ 2 ] [Liang, Fanghua]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China
  • [ 3 ] [Zhang, Yu]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China
  • [ 4 ] [Zhang, Wei]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China
  • [ 5 ] [Wang, Hailou]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China
  • [ 6 ] [Ge, Mingzheng]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China
  • [ 7 ] [Cao, Chunyan]City Univ Hong Kong, Dept Biomed Sci, Hong Kong 999077, Peoples R China
  • [ 8 ] [Dong, Huilong]Changshu Inst Technol, Sch Mat Engn, Changshu 215500, Jiangsu, Peoples R China
  • [ 9 ] [Shao, Huaiyu]Univ Macau, Inst Appl Phys & Mat Engn, Macau 999078, Peoples R China
  • [ 10 ] [Liu, Hongchao]Univ Macau, Inst Appl Phys & Mat Engn, Macau 999078, Peoples R China
  • [ 11 ] [Dong, Kai]Chinese Acad Sci, Beijing Inst Nanoenergy & Nanosyst, Beijing 100083, Peoples R China
  • [ 12 ] [Tang, Yuxin]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 13 ] [Lai, Yuekun]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • 汤育欣 赖跃坤

    [Tang, Yuxin]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China;;[Lai, Yuekun]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China;;[Ge, Mingzheng]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China

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Source :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

Year: 2021

Volume: 416

1 6 . 7 4 4

JCR@2021

1 3 . 4 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:105

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 46

SCOPUS Cited Count: 44

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

Online/Total:128/10000947
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