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author:

Weng, Rengui (Weng, Rengui.) [1] | Tian, Feng (Tian, Feng.) [2] | Yu, Zhendong (Yu, Zhendong.) [3] | Ma, Jiachen (Ma, Jiachen.) [4] | Lv, Yuancai (Lv, Yuancai.) [5] (Scholars:吕源财) | Xi, Beidou (Xi, Beidou.) [6]

Indexed by:

EI SCIE

Abstract:

Currently, Tetrabromobisphenol A (TBBPA) has been regarded as an emerging organic pollutant and efficient TBBPA elimination technology has been attracting increasing attention. In this work, a novel photocatalyst, MoS2/SnIn4S8, was synthesized through hydrothermal method by introducing few-layer MoS2 nanosheets and then employed to establish an integrated photocatalytic reduction/oxidation system for the remediation of TBBPA under visible light. The characterization results demonstrated that the few-layer MoS2 nanosheets were well combined with SnIn4S8 and significantly lowered the recombination rate of the photo-induced electron and holes, leading to outstanding photocatalytic performance of MoS2/SnIn4S8 composite. Besides, the MoS2/SnIn4S8 composite also exhibited excellent reusability (over 10 runs) and stability. The TBBPA degradation experiments showed that the integrated photocatalytic reduction/oxidation system was able to completely degrade TBBPA and mineralize its byproducts (60.2 +/- 2.9%). In the photocatalytic reduction, due to the cleavage of C-Br bonds by photo-induced electrons, TBBPA underwent stepwise debromination and finally transferred into BPA in 6 h. In the following photocatalytic oxidation, under the attack of reactive oxygen species (O-1(2), h(+), (OH)-O-center dot and O-center dot(2)-), BPA was first decomposed into aromatic products (such as phenol, benzoic acid, p-hydroxybenzyl alcohol and so on) via C-C bond cracking and hydroxylation, and then further oxidized into organic acids like maleic acid and muconic acid through ring-opening, and finally mineralized into CO2 and H2O. What was noteworthy was that the final effluent from the photocatalytic reduction/oxidation system showed no toxicity to the luminescent bacteria.

Keyword:

Degradation Metal sulfide photocatalysts Photocatalytic oxidation Photocatalytic reduction TBBPA

Community:

  • [ 1 ] [Weng, Rengui]Fujian Univ Technol, Indoor Environm Engn Res Ctr Fujian Prov, 3 Xueyuan Rd, Fuzhou 350118, Peoples R China
  • [ 2 ] [Tian, Feng]Fujian Univ Technol, Indoor Environm Engn Res Ctr Fujian Prov, 3 Xueyuan Rd, Fuzhou 350118, Peoples R China
  • [ 3 ] [Xi, Beidou]Fujian Univ Technol, Indoor Environm Engn Res Ctr Fujian Prov, 3 Xueyuan Rd, Fuzhou 350118, Peoples R China
  • [ 4 ] [Yu, Zhendong]Fuzhou Univ, Fujian Prov Engn Res Ctr Rural Waste Recycling Te, Dept Environm Sci & Engn, Fuzhou 350116, Peoples R China
  • [ 5 ] [Ma, Jiachen]Fuzhou Univ, Fujian Prov Engn Res Ctr Rural Waste Recycling Te, Dept Environm Sci & Engn, Fuzhou 350116, Peoples R China
  • [ 6 ] [Lv, Yuancai]Fuzhou Univ, Fujian Prov Engn Res Ctr Rural Waste Recycling Te, Dept Environm Sci & Engn, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • 吕源财

    [Xi, Beidou]Fujian Univ Technol, Indoor Environm Engn Res Ctr Fujian Prov, 3 Xueyuan Rd, Fuzhou 350118, Peoples R China;;[Lv, Yuancai]Fuzhou Univ, Coll Environm & Resources, 2 Xueyuan Rd, Fuzhou 350116, Fujian, Peoples R China

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Source :

CHEMOSPHERE

ISSN: 0045-6535

Year: 2021

Volume: 285

8 . 9 4 3

JCR@2021

8 . 1 0 0

JCR@2023

ESI Discipline: ENVIRONMENT/ECOLOGY;

ESI HC Threshold:114

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 34

SCOPUS Cited Count: 39

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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