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author:

Zhu, Junchao (Zhu, Junchao.) [1] | Yang, Tao (Yang, Tao.) [2] | Fu, Yunhan (Fu, Yunhan.) [3] | Sheng, Bibo (Sheng, Bibo.) [4] | Lin, Rongying (Lin, Rongying.) [5]

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EI

Abstract:

Using a simple hydrothermal method, we developed a Si@SnS anode material with SnS nanoparticles uniformly attached to the surface of silicon nanoparticles. Utilizing the first charge-discharge reaction mechanism of SnS, combined with the artificial solid electrolyte interphase to improve the solid electrolyte interphase stability of silicon-based materials and the introduction of conductive additives to improve the conductive properties of silicon-based materials, the Si@SnS material exhibits very excellent performance when applied to lithium-ion battery anodes. At a current density of 0.5A.g−1,after two cycles, the overall resistance of the Si@SnS material battery is reduced by nearly 55% relative to the resistance of the pure silicon battery. As a half-cell anode material, the first coulombic efficiency of Si@SnS at a current density of 1A.g−1 reached 85%, and after 200 cycles, it provided a reversible capacity of 1790 mAh.g−1 and a capacity retention rate of 74.6%. © 2021

Keyword:

Additives Anodes IV-VI semiconductors Layered semiconductors Lithium-ion batteries Nanoparticles Silicon Silicon batteries Solid electrolytes Solid-State Batteries Sulfur compounds Tin compounds

Community:

  • [ 1 ] [Zhu, Junchao]College of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Yang, Tao]College of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 3 ] [Fu, Yunhan]College of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 4 ] [Sheng, Bibo]College of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 5 ] [Lin, Rongying]College of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China

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Source :

Electrochimica Acta

ISSN: 0013-4686

Year: 2021

Volume: 399

7 . 3 3 6

JCR@2021

5 . 5 0 0

JCR@2023

ESI HC Threshold:117

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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