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author:

Chen, Mengting (Chen, Mengting.) [1] | Lai, Yiqing (Lai, Yiqing.) [2] | Zhou, Jiangcong (Zhou, Jiangcong.) [3] | Shi, Chen (Shi, Chen.) [4] | Li, Baojuan (Li, Baojuan.) [5] | Wu, Dewu (Wu, Dewu.) [6] | Wang, Bo (Wang, Bo.) [7] | Ding, Jianyan (Ding, Jianyan.) [8] | Jiang, Xiayi (Jiang, Xiayi.) [9] | Wu, Hongmei (Wu, Hongmei.) [10] | Wu, Quansheng (Wu, Quansheng.) [11]

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EI

Abstract:

As is well known, whitlockite β-Ca3(PO4)2-type phosphors are easily evolved to a new crystal structure by cation substitution, and have various crystallographic sites for doping activators to achieve luminescence. Herein, a novel broadband emitting Sr8MgIn(PO4)7: Eu2+ (SMIP) phosphor was prepared by high temperature solid state reaction. Its crystal structure was analyzed and refined via the Rietveld refinement method. The SMIP crystal presents a monoclinic system with space group C2/m. Their diffuse reflection and excitation spectra both show an intense absorption to the wavelength of 250–500 nm. And the photoluminescence spectrum exhibits a strong broadband emitting from 450 to 800 nm. Moreover, the luminescence decay curves reveal three kinds of Sr/Mg2+ crystallographic sites for Eu2+ occupying in SMIP host. For SMIP: xEu2+ samples, the optimized doping concentration was determined to be 0.03, and the energy transfer among the nearest-neighbor was dominating. Further, the activation energy was estimated to be 0.1145 eV. Finally, white light-emitting diodes (WLED) lamps were fabricated by coating the mixtures of SMIP: 0.03Eu2+ phosphors and BaMgAl10O17: Eu2+ phosphors on the surface of 400 nm near-ultraviolet chip. The optimized WLED lamp exhibits a correlated color temperature of 3034 K and a good color rendering index of 91.7. These results demonstrate the commercialized prospect of SMIP: Eu2+ materials as a broadband orange phosphor for application of solid state lighting. © 2021 Elsevier B.V.

Keyword:

Activation energy Citrus fruits Color Crystal structure Energy transfer High temperature applications Light emitting diodes Luminescence Phosphors Photoluminescence spectroscopy Rietveld refinement Solid state reactions

Community:

  • [ 1 ] [Chen, Mengting]College of Materials Science and Engineering, Fuzhou University, Fujian; 350108, China
  • [ 2 ] [Chen, Mengting]College of Chemistry & Materials Science, Longyan University, Fujian; 364000, China
  • [ 3 ] [Lai, Yiqing]College of Materials Science and Engineering, Fuzhou University, Fujian; 350108, China
  • [ 4 ] [Lai, Yiqing]College of Chemistry & Materials Science, Longyan University, Fujian; 364000, China
  • [ 5 ] [Zhou, Jiangcong]College of Materials Science and Engineering, Fuzhou University, Fujian; 350108, China
  • [ 6 ] [Zhou, Jiangcong]College of Chemistry & Materials Science, Longyan University, Fujian; 364000, China
  • [ 7 ] [Shi, Chen]College of Materials Science and Engineering, Fuzhou University, Fujian; 350108, China
  • [ 8 ] [Li, Baojuan]College of Chemistry & Materials Science, Longyan University, Fujian; 364000, China
  • [ 9 ] [Wu, Dewu]College of Chemistry & Materials Science, Longyan University, Fujian; 364000, China
  • [ 10 ] [Wang, Bo]School of Applied Physics and Materials, Wuyi University, Guangdong; 529020, China
  • [ 11 ] [Ding, Jianyan]College of Chemistry & Materials Science, Longyan University, Fujian; 364000, China
  • [ 12 ] [Jiang, Xiayi]College of Chemistry & Materials Science, Longyan University, Fujian; 364000, China
  • [ 13 ] [Wu, Hongmei]College of Chemistry & Materials Science, Longyan University, Fujian; 364000, China
  • [ 14 ] [Wu, Quansheng]College of Materials Science and Engineering, Fuzhou University, Fujian; 350108, China
  • [ 15 ] [Wu, Quansheng]College of Chemistry & Materials Science, Longyan University, Fujian; 364000, China

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Source :

Optical Materials

ISSN: 0925-3467

Year: 2021

Volume: 115

3 . 7 5 4

JCR@2021

3 . 8 0 0

JCR@2023

ESI HC Threshold:142

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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