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author:

Liu, L. (Liu, L..) [1] | Zhong, Q. (Zhong, Q..) [2] | Jiang, L. (Jiang, L..) [3] | Li, P. (Li, P..) [4] | Xiao, L. (Xiao, L..) [5] | Gong, Y. (Gong, Y..) [6] | Zhu, Z. (Zhu, Z..) [7] | Yang, J. (Yang, J..) [8]

Indexed by:

Scopus

Abstract:

Located in Pujiang, Chengdu, China, more than four hundred artifacts were unearthed during the excavation of the Warring States (the Warring States period lasts from 475 to 221 BC) ship-shaped graves in 2016. The compositional and metallurgical feature of the unearthed vessels are still unclear. Archaeologists and conservators are puzzled by such problems that need to be answered by systematic scientific studies. Fifty one samples, either from the matrix (26 samples), or from the corrosion part (25 samples) of 25 unearthed bronze vessels, were carefully collected from the fallen part of the bronze vessels for analysis. Technical methods, such as OM, SEM-EDS, XRD and Raman Spectroscopy were adopted for compositional and metallurgical characterization of the bronzes, as well as identification of the corrosion products. The bronzes are Cu–Sn–Pb trinary alloys with typical casting microstructure. The proportion of Sn are in accordance with excavated bronze vessels in surrounding areas. Recycling isn’t involved with the production of such vessels. Layered structure of the corrosion products was observed. Different corrosion products were identified as Cu2CO3(OH)2, Cu2O, CuSO4·5H2O SnO2, PbSO4 and PbCO3. The findings help us gain insights into the bronze manufacturing in Bashu district, as well as the corrosion behavior in certain condition. © 2022, The Author(s).

Keyword:

Bronze vessel Compositional analysis Metallurgical characterization The Warring States Period

Community:

  • [ 1 ] [Liu, L.]Xiamen Academy of Arts and Design, Fuzhou University, Xiamen, 361000, China
  • [ 2 ] [Zhong, Q.]State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University, Xi’an, 710072, China
  • [ 3 ] [Jiang, L.]Chengdu Institute of Cultural Relics and Archaeology, Chengdu, 610042, China
  • [ 4 ] [Li, P.]Chengdu Institute of Cultural Relics and Archaeology, Chengdu, 610042, China
  • [ 5 ] [Xiao, L.]Chengdu Institute of Cultural Relics and Archaeology, Chengdu, 610042, China
  • [ 6 ] [Gong, Y.]Chengdu Institute of Cultural Relics and Archaeology, Chengdu, 610042, China
  • [ 7 ] [Zhu, Z.]Conservation Science Laboratory, Department of History, College of Humanities, Xiamen University, Xiamen, 361005, China
  • [ 8 ] [Zhu, Z.]Department of Archaeology, Max Planck Institute for the Science of Human History, Jena, D-07745, Germany
  • [ 9 ] [Yang, J.]Xiamen Academy of Arts and Design, Fuzhou University, Xiamen, 361000, China
  • [ 10 ] [Yang, J.]State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University, Xi’an, 710072, China
  • [ 11 ] [Yang, J.]Institute of Culture and Heritage, Northwestern Polytechnical University, Xi’an, 710072, China

Reprint 's Address:

  • [Yang, J.]Xiamen Academy of Arts and Design, China;;[Zhu, Z.]Conservation Science Laboratory, China

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Source :

Heritage Science

ISSN: 2050-7445

Year: 2022

Issue: 1

Volume: 10

2 . 5

JCR@2022

2 . 6 0 0

JCR@2023

ESI HC Threshold:117

JCR Journal Grade:2

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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